Process for producing polymer foam using mixtures of pentafluoropropane and a hydrofluorocarbon having 3 to 6 carbon atoms

ABSTRACT

The invention discloses novel azeotrope-like mixtures of fluorinated compounds which are useful for heating and cooling as heat transfer agents and/or refrigerants. The azeotrope-like mixture comprises: (a) pentafluoropropane; and (b) a hydrofluorocarbon of the formula: C x F y H z , wherein x is 3, 4, 5, or 6 and y and z are each independently 1 or a positive whole number such that the result of y/(y+z) is greater than 0.67.

RELATED APPLICATIONS

This is divisional of application, Ser. No. 08/685,821, filed on Aug. 31. 1998, now U.S. Pat. No. 5,800,729 which is a continuation-in-part application of Ser. No. 60/001,530, filed Jul. 26, 1995.

BACKGROUND OF THE INVENTION

1. Field of the Invention

This invention relates to mixtures of pentafluoropropane and a hydrofluorocarbon having 3 to 6 carbon atoms. These mixtures are useful as refrigerants for heating and cooling.

2. Description of Related Art

Fluorocarbon based fluids have found widespread use in industry for refrigeration applications such as air conditioning and heat pump applications. Vapor compression is one type of refrigeration. In its simplest form, vapor compression involves changing the refrigerant from the liquid to the vapor phase through heat absorption at low pressure and then from the vapor to the liquid phase through heat removal at an elevated pressure.

The primary purpose of refrigeration is to remove energy at low temperature. The primary purpose of a heat pump is to add energy at higher temperature. Heat pumps are considered reverse cycle systems because, for heating, the operation of the condenser is interchanged with that of the refrigeration evaporator.

Certain chlorofluoromethane and chlorofluoroethane derivatives have gained widespread use in refrigeration applications including air conditioning and heat pump applications owing to their unique combination of chemical and physical properties. The majority of refrigerants utilized in vapor compression systems are either single component fluids or azeotropic mixtures. Moreover, certain applications, such as centrifugal chillers, can only use pure or azeotropic refrigerants because non-azeotropic mixtures will separate in pool boiling evaporators resulting in undesirable performance. In other applications, non-azeotropic (or zeotropic) refrigerants may be used.

Azeotropic or azeotrope-like compositions are particularly desirable because they do not fractionate on boiling. This behavior is desirable because in the vapor compression equipment in which these refrigerants are employed, condensed material is generated in preparation for cooling or heating purposes. Unless the refrigerant composition exhibits a constant boiling point, i.e., is azeotrope-like, fractionation and segregation will occur on evaporation and condensation producing undesirable refrigerant distribution which may upset the cooling or heating. If a leak occurs in a refrigeration system during use or service, the composition of the azeotrope-like mixture does not change and, thus, the system pressures and performance remain unaffected.

The art continually seeks new fluorocarbon based azeotrope-like as well as zeotropic mixtures that offer alternatives for refrigeration and heat pump applications. Currently of interest are fluorocarbon based mixtures that are considered to be environmentally safe substitutes for the fully halogenated chlorofluorocarbons (CFC's) presently used that are suspected of causing environmental problems in connection with the earth's protective ozone layer.

The substitute material must also possess those properties unique to the CFC's being replaced including chemical stability, low toxicity, non-flammability, and efficiency in use. The latter characteristic is important in refrigeration and air conditioning especially where a loss in refrigerant thermodynamic performance or energy efficiency may have secondary environmental impacts through increased fossil fuel use arising from an increased demand for electrical energy. Furthermore, the ideal CFC refrigerant substitute would not require major engineering changes to conventional vapor compression equipment currently used with CFC refrigerants.

Mathematical models have substantiated that hydrofluorocarbons such as pentafluoropropane, including 1,1,2,2,3-pentafluoropropane (HFC-245ca), 1,1,2,3,3-pentafluoropropane (HFC-245ea), 1,1,1,2,3-pentafluoropropane (HFC-245eb), and 1,1,1,3,3-pentafluoropropane (HFC-245fa) will not adversely affect atmospheric chemistry because these hydrofluorocarbons are negligible contributors to ozone depletion and to “green-house” global warming in comparison to fully halogenated species.

However, 245eb has been found to have flame limits under normal ambient conditions and HFC-245ca and HFC-245fa have been found to have flame limits under certain conditions. It has not been confirmed whether or not the other pentafluoropropane isomer also exhibits some finite flame propagation behavior in specific environments. This flame propagation behavior would significantly limit the potential use of pentafluoropropane isomers in refrigerant applications.

SUMMARY OF THE INVENTION

In accordance with this invention, novel mixtures have been discovered comprising pentafluoropropane (HFC-245) and a hydrofluorocarbon of the formula C_(x)F_(y)H_(z) wherein x is 3, 4, 5, or 6 and y and z are each independently 1 or a positive whole number such that the product of y/(y+z) is greater than 0.67. Preferably, the 245 isomer is either 245ca or 245fa, most preferably 245fa. A second aspect of this invention is a cooling process in which any of the refrigerants of this invention are condensed and then evaporated in the vicinity of an object to be cooled. Additionally, the same process may be used to heat an object in the vicinity of the condensing refrigerant. Both the heating and cooling processes may be characterized as processes for transferring heat by condensing the refrigerant in a first region to be heated, transferring the refrigerant to a second region to be cooled, and evaporating the refrigerant in the region to be cooled.

The compositions of the invention comprise, consist essentially or consist of azeotrope-like or zeotropic mixtures. Azeotrope-like characteristics are inherent in those compositions in which an azeotropic system exists. In such systems, the precise azeotropic compositions have not been determined but have been ascertained to be within the ranges indicated herein. In general, in such systems, the azeotrope-like compositions exhibit vapor pressures within about ±5 psia and preferably within about ±2 psia (at 0° C.) of the vapor pressure of the true azeotrope (at 0° C.).

DETAILED DESCRIPTION OF THE INVENTION AND PREFERRED EMBODIMENTS

The following discussion relates to those compositions which are azeotrope-like.

From fundamental principles, the thermodynamic state of a fluid is defined by four variables: pressure, temperature, liquid composition and vapor composition, P, T, X, and Y, respectively. An azeotrope is a unique characteristic of a system of two or more components in which X and Y are equal at the state P and T. In practice, this means that the components of a mixture cannot be separated during a phase change and, therefore, are useful in cooling and heating applications. Azeotrope-like means that the composition behaves like an azeotrope, i.e., has constant boiling characteristics or a tendency not to fractionate on boiling or evaporation. In such compositions, the composition of the vapor formed during boiling or evaporation is identical or substantially identical to the original liquid composition. During boiling or evaporation, the liquid composition changes, if at all, only minimally. In contrast, non-azeotrope-like compositions change to a substantial degree during boiling or evaporation.

The azeotrope-like compositions of this invention exhibit essentially constant vapor pressure characteristics as the liquid mixture is evaporated and show relatively minor shifts in composition during evaporation. Thus, the compositions are advantageously used in a vapor compression cycle because they mimic the performance of a constant boiling single component or azeotropic mixture refrigerant.

Another characteristic of azeotrope-like compositions is that there is a range of compositions containing the same components in varying proportions that are azeotrope-like or constant boiling. All such compositions are intended to be covered by the terms “azeotrope-like” or “constant boiling” as used herein. As an example, it is well known that at differing pressures, the composition of a given azeotrope will vary at least slightly as does the boiling point of the composition. Thus, an azeotrope of A and B represents a unique relationship, but with a variable composition depending on temperature and/or pressure. As is readily understood by persons ordinarily skilled in the art, the boiling point of the azeotrope will vary with the pressure.

The compositions of this invention may include additional components. In the embodiment where azeotrope-like compositions are involved, the preferred additional components are those which do not form new azeotropic or azeotrope-like systems.

In other words, additional components that are not present in a first distillation cut taken. One way to determine whether the addition of a component forms a new azeotropic or azeotrope-like system is to distill a sample of the system under conditions, such as with reflux, that would be expected to separate the mixture into its separate components. If the mixture containing the additional component is non-azeotropic or non-azeotrope-like, the additional component will fractionate from the azeotropic or azeotrope-like components. If the mixture is azeotrope-like, some finite amount of a first distillation cut will be obtained that contains all of the mixture components and is constant boiling or behaves as a single substance. As used herein, “first distillation cut” means the first cut taken after the distillation column displays the steady state operation under total reflux conditions.

The additional components that may be used include those components added to tailor the properties of the composition to the end use. For example, it is known to add propane to refrigerant compositions to aid solubility, with commercial refrigeration lubricants. Other suitable additional components will be readily apparent to those, ordinarily skilled in the art.

As such, the present invention meets the need in the art for a refrigerant that has a low ozone depletion potential and is a negligible contributor to global warming compared to fully halogenated CFC refrigerants. Further, the compositions of the invention are nonflammable, have a coefficient of performance and capacity suitable for use as replacement refrigerants, and have low compressor discharge temperatures. In one process embodiment of the invention, the compositions of the invention may be used in a method for producing refrigeration that comprises condensing a refrigerant comprising the compositions of the invention and, subsequently, evaporating the refrigerant in the vicinity of a body to be cooled. Alternatively, the compositions of this invention may be used in a method for producing heating that comprises condensing a refrigerant composition comprising the compositions of this invention in the vicinity of a body to be heated and then evaporating the refrigerant.

The compositions of this invention may also be used as heat transfer fluids. For example, in certain refrigeration systems, it is desirable to operate the system at a specific temperature. However, maintaining the desired temperature may require the addition or removal of heat. Thus, a secondary heating loop containing an appropriate heat transfer fluid may be added. The heat transfer fluid absorbs heat in one part of the cycle and transfers the heat to another part of the cycle without changing state when the heat transferred is sensible heat, or by changing state when the heat transferred is latent heat.

In another process embodiment of the invention, the compositions of this invention are used in a method for producing polyurethane and polyisocyanurate foams. The method comprises reacting and foaming a mixture of ingredients that forms the polyurethane and polyisocyanurate foams in the presence of a volatile blowing agent comprising the compositions of this invention. The blowing agents of this invention are used alone or in a premix with a polyol. The premix comprises the compositions of this invention prior to reaction and foaming of the ingredients forming polyurethane and polyisocyanurate foams. Suitable polyols for the premix are known in the art, for example in U.S. Pat. No. 5,130,345 incorporated in its entirety herein by reference.

In yet another process embodiment, the compositions of this invention may be used in a method for producing foam comprising blending heat plasticized resin with a volatile blowing agent comprising the compositions of this invention and introducing the resin/volatile blowing agent blend into a zone of lower pressure to cause foaming. The compositions of this invention may also be used in a method of dissolving contaminants or removing contaminants from the surface of a substrate. This use comprises the step of contacting the substrate with the compositions. The compositions of this invention may also be used as fire extinguishing agents or as volatile carrier fluids or propellants in aerosol formulations.

Preferably, the materials used to form the compositions of this invention are used in sufficiently high purity so as to avoid the introduction of adverse influences on the cooling or heating properties or constant boiling properties of the azeotrope-like embodiments of the invention. The invention is illustrated in the following Tables 1 through 4. With respect to these Tables, it is to be understood that the specified composition weight percentages are prefaced by the term “about”; and NBP refers to the normal boiling point; VP refers to vapor pressure equal to 0.99 atm and also the chemical structures are shown with letters and numbers with the understanding that in these structures, the capital letters are on the line and the numbers are in subscript to create the standard chemical formula notation.

These mixtures are used in conventional heating and/or cooling equipment as is described in numerous U.S. patents and published articles.

In a preferred embodiment, the azeotrope-like mixture comprises 1,1,2,2,3-pentafluoropropane, and the hydrofluorocarbon which is independently selected from the 245ca components of Table 1, and is present in the mixture at or between the upper and lower values by weight percent for the preferred, more preferred or most preferred ranges as shown in Table 1.

In a preferred embodiment, the azeotrope-like mixture comprises 1,1,2,3,3-pentafluoropropane, and the hydrofluorocarbon is independently selected from the 245ea azeotrope components of Table 2 is present in the mixture at or between the upper and lower values by weight percent for the preferred, more preferred, or most preferred ranges as shown in Table 2.

In a preferred embodiment, the azeotrope-like mixture comprises 1,1,1,2,3-pentafluoropropane, and the hydrofluorocarbon is independently selected from the 245eb azeotrope components of Table 3 is present in the mixture at or between the upper and lower values by weight percent for the preferred, more preferred, or most preferred ranges shown in Table 3.

In a preferred embodiment, the azeotrope-like mixture comprises 1,1,1,3,3-pentafluoropropane, and the hydrofluorocarbon is independently selected from the 245fa azeotrope components of Table 4 is present in the mixture at or between the upper and lower values by weight percent for the preferred. more preferred, or most preferred ranges as shown in Table 4.

TABLE 1 245 ca azeotropes at 25° C. 245 ca Preferred 245 ca More preferred 245 ca Most preferred Azeo NBP = 25.4° C. VP = 0.99 atm Compositions (wt. %) Compositions (wt. %) Compositions (wt. %) NBP STRUCTURE est. BP (° C.) Upper Lower Upper Lower Upper Lower (±1) CF3CF2CF2CH2CH3 46.3 51 99 61 99 70 89 20 CF3CF2CH2CF2CH3 59.4 57 99 67 99 75 91 22 CF3CF2CHFCHFCH3 61.7 58 99 68 99 76 91 23 CF2CH2CF2CF2CH3 67.2 60 99 70 99 77 92 23 CF3CHFCF2CHFCH3 68 60 99 70 99 77 92 23 CF3CHFCHCF2CH3 72.9 62 99 72 99 79 92 24 CF3CF2CHFCH2CH2F 70 61 99 71 99 78 92 24 CF3CF2CH2CHFCH2F 75.2 63 99 73 99 80 93 24 CF3CHFCF2CH2CH2F 76.8 64 99 74 99 80 93 24 CF3CHFCH2CF2CH2F 83.1 66 99 76 99 82 93 24 CF3CH2CF2CHFCH2F 84.2 66 99 76 99 82 93 24 CF3CH2CHFCF2CH2F 85.4 67 99 77 99 82 93 24 CF3CHFCHFCHFCH2F 89.1 68 99 78 99 83 94 24 CF3CF2CH2CH2CHF2 72.5 62 99 72 99 79 92 24 CF3CH2CH2CF2CHF2 80.4 65 99 75 99 81 93 24 CF3CH2CF2CH2CHF2 82 65 99 75 99 81 93 24 CF3CHFCHFCH2CHF2 865 67 99 77 99 82 93 24 CF3CHFCH2CHFCHF2 877 67 99 77 99 83 94 24 CF3CH2CHFCHFCHF2 90.4 68 99 78 99 83 94 24 CF3CH2CH2CHFCF3 72.9 62 99 72 99 79 92 24 CF3CH2CHFCH2CF3 75.7 63 99 73 99 80 93 24 CHF2CHFCHFCHF2 65.1 63 99 73 99 80 93 23 CHF2CF2CHFCH2F 55.3 59 99 69 99 77 92 22 CHF2CHFCF2CH2F 57.5 60 99 70 99 77 92 22 CH2FCF2CF2CH2F 49.2 57 99 67 99 75 91 21 CHF2CF2CF2CH3 35.8 50 99 60 99 70 89 20 CF3CF2CHFCH3 26 45 95 55 95 65 85 19 CF3CHFCF2CH3 32 48 95 58 95 67 86 20 CF3CHFCHFCF2CHFCH2F 120.9 72 99 82 99 86 95 24 CF3CF2CF2CF2CHFCH2F 112.7 70 99 80 99 85 94 24 CF3CF2CHFCH2CF2CH2F 106.9 68 99 78 99 84 94 24 CF3CHFCF2CH2CF2CH2F 111.2 70 99 80 99 84 94 24 CF3CF2CH2CHFCF2CH2F 110.3 69 99 79 99 84 94 24 CF3CHFCHFCHFCF2CH2F 121.8 72 99 82 99 87 95 24 CF3CH2CF2CFHCF2CH2F 114.2 70 99 80 99 85 94 24 CF3CHFCH2CF2CF2CH2F 113.4 70 99 80 99 85 94 24 CF3CH2CHFCF2CF2CH2F 113.1 70 99 80 99 85 94 24 CF3CHFCH2CF2CHFCHF2 120.9 72 99 82 99 86 95 24 CF3CH2CHFCF2CHFCHF2 122.2 72 99 82 99 87 95 24 CF2CF2CH2CH2CF2CHF2 104.6 68 99 78 99 83 94 24 CF3CHFCHFCH2CF2CHF2 117.8 71 99 81 99 86 95 24 CF3CH2CF2CH2CF2CHF2 112.4 70 99 80 99 85 94 24 CF3CHFCH2CHFCF2CHF2 117.3 71 99 81 99 86 95 24 CF3CH2CH2CF2CF2CHF2 107.3 68 99 78 99 84 94 24 CHF2CF2CF2CH2CF2CH2F 114.1 70 99 80 99 85 94 24 CHF2CF2CHFCHFCF2CH2F 125.4 73 99 83 99 87 95 24 CHF2CHFCF2CHFCF2CH2F 125 73 99 83 99 87 95 24 CHF2CF2CH2CF2CF2CH2F 117.5 71 99 81 99 86 95 24 CHF2CHFCHFCF2CF2CH2F 124.2 73 99 83 99 87 95 24 CHF2CH2CF2CF2CF2CH2F 112.2 70 99 80 99 85 94 24 CF2HCF2CF2CF2CHFCH3 94.4 64 99 74 99 81 93 24 CF2HCF2CF2CHFCF2CH3 100.8 67 99 77 99 82 93 24 CHF2CF2CHFCF2CF2CH3 104.2 68 99 78 99 83 94 24 CHF2CHFCF2CF2CF2CH3 101.4 67 99 77 99 82 93 24 CH2FCF2CF2CF2CF2CH3 90.6 63 99 73 99 80 93 24 CH2FCF2CF2CF2CHFCH2F 110.9 69 99 79 99 84 94 24 CH2FCF2CF2CHECF2CH2F 115.9 71 99 81 99 85 94 24 CF3CH2CH2CHFCF2CF3 96.7 65 99 75 99 81 93 24 CF3CH2CH2CF2CHFCF3 104.4 68 99 78 99 83 94 24 CF3CF2CH2CHFCH2CF3 100.7 66 99 76 99 82 93 24 CF3CHFCHFCHFCH2CF3 115.5 71 99 81 99 85 94 24 CF3CH2CF2CHFCH2CF3 111.4 70 99 80 99 84 94 24 CF3CHFCH2CF2CH2CF3 108.4 69 99 79 99 84 94 24 CF3CHFCH2CH2CF2CF3 97.1 65 99 75 99 81 93 24 CF3CHFCHFCH2CHFCF3 112 70 99 80 99 85 94 24 CF3CF2CF2CH2CH2CHF2 95.9 65 99 75 99 81 93 24 CF3CF2CHFCHFCH2CHF2 111.2 70 99 80 99 84 94 24 CF3CHFCF2CHFCH2CHF2 116.6 71 99 81 99 86 95 24 CF3CF2CH2CF2CH2CHF2 107.9 69 99 79 99 84 94 24 CF3CHFCHFCF2CH2CHF2 120.5 72 99 82 99 86 95 24 CF3CH2CF2CF2CH2CHF2 114 70 99 80 99 85 94 24 CF3CF2CHFCH2CHFCHF2 111.5 70 99 80 99 84 94 24 CF3CHFCF2CH2CHFCHF2 117.4 71 99 81 99 86 95 24 CF3CF2CH2CHFCHFCHF2 115.4 71 99 81 99 85 94 24 CF3CHFCHFCHFCHFCHF2 128.5 74 99 84 99 88 95 24 CF3CH2CF2CHFCHFCHF2 122.7 73 99 83 99 87 95 24 CF3CF2CF2CHFCH2CH2F 94.3 64 99 74 99 81 93 24 CF3CF2CHFCF2CH2CH2F 102.3 67 99 77 99 82 93 24 CF3CHFCF2CF2CH2CH2F 105.3 68 99 78 99 83 94 24 CF3CF2CF2CH2CHFCH2F 98.6 66 99 76 99 82 93 24 CF3CF2CHFCHFCHFCH2F 113.8 70 99 80 99 85 94 24 CF3CHFCF2CHFCHFCH2F 117.5 71 99 81 99 86 95 24 CF3CF2CH2CF2CHFCH2F 110 69 99 79 99 84 94 24 CH3CHFCF2CF2CF3 50.2 50 99 60 99 70 89 22 CH3CF2CFHCF2CF3 57.5 54 99 64 99 73 90 22 CH3CF2CF2CHFCF3 60.9 55 99 65 99 74 91 23 CH2FCH2CF2CF2CF3 60.7 55 99 65 99 74 91 23 CH2FCHFCHFCF2CF3 75.5 61 99 71 99 78 92 24 CH2FCHFCF2CHFCF3 80.1 63 99 73 99 79 92 24 CH2FCF2CH2CF2CF3 71.6 60 99 70 99 77 92 24 CH2FCF2CHFCHFCF3 83.5 64 99 74 99 80 93 24 CH2FCF2CF2CH2CF3 76.1 61 99 71 99 78 92 24 CF2HCH2CHFCF2CF3 74.6 61 99 71 99 78 92 24 CF2HCH2CF2CHFCF3 79.7 63 99 73 99 79 92 24 CF2HCHFCH2CF2CF3 77.9 62 99 72 99 79 92 24 CF2HCHFCHFCHFCF3 90.2 66 99 76 99 82 93 24 CF2HCHFCF2CH2CF3 83.5 64 99 74 99 80 93 24 CF2HCF2CH2CFHCF3 82 63 99 73 99 80 93 24 CF2HCF2CHFCH2CF3 82.6 64 99 74 99 80 93 24 CF3CH2CH2CF2CF3 64.8 57 99 67 99 75 91 24 CF3CH2CHFCHFCF3 77.2 62 99 72 99 79 92 24 CF3CH2CF2CH2CF3 71 59 99 69 99 77 92 24 CF3CHFCH2CHFCF3 76.2 61 99 71 99 78 92 24 CH2FCF2CHFCF2CF2H 85.4 65 99 75 99 81 93 24 CH2FCF2CF2CHFCF2H 85.2 65 99 75 99 81 93 24 CH2FCHFCF2CF2CF2H 81.3 63 99 73 99 80 93 24 CH3CF2CF2CF2CF2H 60.9 55 99 65 99 74 91 23 CF2HCH2CF2CF2CF2H 82.6 64 99 74 99 80 93 24 CF2HCHFCHFCF2CF2H 93.8 67 99 77 99 83 94 24 CF2HCHFCF2CHFCF2H 94.3 68 99 78 99 83 94 24 CF2HCF2CH2CF2CF2H 86.1 65 99 75 99 81 93 24 CH2FCF2CF2CF2CH2F 74.3 61 99 71 99 78 92 24 CF3CF2CF2CH2CH2CF3 88.3 61 99 71 99 78 92 24 CF3CF2CHFCHFCH2CF3 101.9 65 99 75 99 81 93 24 CH3CHFCF2CHFCH2CF3 107.3 67 99 77 99 82 93 24 CF3CF2CH2CF2CH2CF3 96.9 64 99 74 99 80 93 24 CF3CHFCHFCF2CH2CF3 109.5 68 99 78 99 83 94 24 CF3CH2CF2CF2CH2CF3 103 66 99 76 99 81 93 24 CF3CHFCH2CHFCF2CF3 100 65 99 75 99 81 93 24 CF3CHFCH2CF2CHFCF3 106 26 99 36 99 52 83 24 CF3CHFCHFCH2CF2CF3 102.2 65 99 75 99 81 93 24 CF3CHFCHFCHFCHFCF3 115.3 69 99 79 99 84 94 24 CF3CF2CH2CH2CF2CF3 89 61 99 71 99 78 92 24 CH3CF2CF2CHFCH2CHF2 98.8 64 99 74 99 80 93 24 CF3CF2CHFCF2CH2CHF2 105.1 66 99 76 99 82 93 24 CF3CHFCF2CF2CHFCHF2 108.2 67 99 77 99 83 94 24 CF3CF2CF2CH2CHFCHF2 101.4 65 99 75 99 81 93 24 CF3CF2CHFCHFCHFCHF2 114.8 69 99 79 99 84 94 24 CF3CHFCF2CHFCHFCHF2 118.6 70 99 80 99 85 94 24 CF3CF2CH2CF2CHFCHF2 109.4 68 99 78 99 83 94 24 CF3CHFCHFCF2CHFCHF2 120.3 71 99 81 99 85 94 24 CF3CH2CF2CF2CHFCHF2 112.1 68 99 78 99 83 94 24 CF3CF2CHFCH2CF2CHF2 105.8 66 99 76 99 82 93 24 CF3CHFCF2CH2CF2CHF2 110.1 68 99 78 99 83 94 24 CF3CF2CH2CHFCF2CHF2 107.5 67 99 77 99 82 93 24 CF3CHFCHFCHFCF2CHF2 118.9 70 99 80 99 85 94 24 CF3CH2CF2CHFCF2CHF2 111.4 68 99 78 99 83 94 24 CF3CHFCH2CF2CF2CHF2 108.9 67 99 77 99 83 94 24 CF3CH2CHFCF2CF2CHF2 108.5 67 99 77 99 83 94 24 CF3CF2CF2CF2CH2CH2F 85.8 60 99 70 99 77 92 24 CF3CF2CF2CHFCHFCH2F 99.7 65 99 75 99 81 93 24 CF3CF2CHFCF2CHFCH2F 105.6 66 99 76 99 82 93 24 CF3CHFCF2CF2CHFCH2F 106.9 67 99 77 99 82 93 24 CH3CF2CF2CH2CF2CH2F 95.1 63 99 73 99 80 93 24 CF3CF2CHFCHFCF2CH2F 108.1 67 99 77 99 83 94 24 CF3CHFCF2CHFCF2CH2F 110.1 68 99 78 99 83 94 24 CF3CF2CH2CF2CF2CH2F 101.9 65 99 75 99 81 93 24 CF3CHFCHFCF2CF2CH2F 111.4 68 99 78 99 83 94 24 CHF2CF2CHFCF2CF2CH2F 101.2 65 99 75 99 81 93 24 CF3CF2CF2CF2CHFCH3 75.4 56 99 66 99 74 91 24 CF3CF2CF2CF2CF2CH3 81.8 58 99 68 99 76 91 24 CF3CF2CHFCF2CF2CH3 86.9 60 99 70 99 77 92 24 CF3CHFCF2CF2CF2CH3 86.6 60 99 70 99 77 92 24 CHF2CF2CF2CHFCHFCHF2 119.8 70 99 80 99 85 94 24 CHF2CF2CHFCF2CHFCHF2 122.2 71 99 81 99 86 95 24 CHF2CHFCF2CF2CHFCHF2 121.2 71 99 81 99 85 94 24 CHF2CF2CF2CF2CF2CHF2 113 69 99 79 99 84 94 24 CHF2CF2CHFCHFCF2CHF2 122.6 71 99 81 99 86 95 24 CHF2CH2CF2CF2CF2CHF2 107.7 67 99 77 99 83 94 24 CHF2CF2CF2CF2CHFCH2F 106.4 67 99 77 99 82 93 24 CHF2CF2CF2CHFCF2CH2F 111.4 68 99 78 99 83 94 24 CHF2CF2CHFCF2CF2CH2F 113.1 69 99 79 99 84 94 24 CHF2CHFCF2CF2CF2CH2F 110.3 68 99 78 99 83 94 24 CH2FCF2CF2CF2CF2CH2F 99.4 65 99 75 99 81 93 24 CHFCF2CF2CF2CF2CH3 86.1 60 99 70 99 77 92 24 CHFC3CF2CF2CF3 16.8 38 80 48 80 56 72 13 CH2FCHFCF2CF3 38 49 95 59 95 68 86 19 CH2FCF2CHFCF3 42.6 51 99 61 99 70 89 20 CH2FCF2CH2CF3 44.7 52 99 62 99 71 90 20 CF2HCH2CF2CF3 40.2 50 99 60 99 70 89 20 CF2HCHFCHFCF3 51.9 55 99 65 99 74 91 21 CF3CH2CHFCF3 41.5 50 99 60 99 70 89 20 CH2FCF2CF2CF2H 44.7 52 99 62 99 71 90 20 CF2HCHFCF2CF2H 54.7 56 99 66 99 75 91 21 CF3CF2CHFCH2CF3 65.3 55 99 65 99 74 91 CF3CH2CF2CHFCF3 68.6 56 99 66 99 75 91 24 CF3CHFCH2CF2CF3 66.5 56 99 66 99 74 91 24 CF3CHFCHFCHFCF3 77 60 99 70 99 77 92 24 CF3CH2CF2CF2CHF2 71.6 58 99 68 99 75 91 24 CF3CHFCHFCF2CHF2 80.6 61 99 71 99 78 92 24 CF3CF2CH2CF2CHF2 70.5 57 99 67 99 75 91 24 CF3CHFCF2CHFCHF2 79.5 61 99 71 99 78 92 24 CF3CF2CHFCHFCHF2 76.5 60 99 70 99 77 92 24 CF3CF2CF2CH2CHF2 63.6 54 99 64 99 73 90 24 CF3CF2CF2CHFCH2F 62.3 54 99 64 99 73 90 24 CF3CF2CHFCF2CH2F 68.1 56 99 66 99 74 91 24 CF3CHFCF2CF2CH2F 70.3 57 99 67 99 75 91 24 CF3CF2CF2CF2CH3 41.9 45 99 55 99 66 88 24 CHF2CF2CF2CHFCHF2 80.7 61 99 71 99 78 92 24 CHF2CF2CHFCF2CHF2 82.6 62 99 72 99 79 92 24 CHF2CF2CF2CF2CH2F 69.8 57 99 67 99 75 91 24 CH3(CF2)4CF3 67.1 51 99 61 99 71 90 24 CH2FCHF(CF2)3CF3 87.4 59 99 69 99 76 91 24 CH2FCF2CHFCF2CF2CF3 92.3 61 99 71 99 78 92 24 CH2FCF2CF2CHFCF2CF3 95.8 62 99 72 99 79 92 24 CH2F(CF2)3CHFCF3 95.4 62 99 72 99 79 92 24 CF2HCH2(CF2)3CF3 88.7 59 99 69 99 77 92 24 CF2HCHFCHFCF2CF2CF3 100.8 63 99 73 99 80 93 24 CF2HCHFCF2CHFCF2CF3 104.9 65 99 75 99 81 93 24 CF2HCHFCF2CF2CHFCF3 106.3 65 99 75 99 81 93 24 CF2HCF2CH2CF2CF2CF3 94 61 99 71 99 78 92 24 CF2HCF2CHFCHFCF2CF3 105.3 65 99 75 99 81 93 24 CF2HCF2CHFCF2CHFCF3 107.3 65 99 75 99 81 93 24 CF2HCF2CF2CH2CF2CF3 97.4 62 99 72 99 79 92 24 CF2HCF2CF2CHFCHFCF3 106.6 65 99 75 99 81 93 24 CF3CF2CHFCHFCHF2 76.5 60 99 70 99 77 92 24 CF3CF2CF2CH2CHF2 63.6 54 99 64 99 73 90 24 CF3CF2CF2CHFCH2F 62.3 54 99 64 99 73 90 24 CF3CF2CHFCF2CH2F 68.1 56 99 66 99 74 91 24 CF3CHFCF2CF2CH2F 70.3 57 99 67 99 75 91 24 CF3CF2CF2CF2CH3 41.9 45 99 55 99 66 88 24 CHF2CF2CF2CHFCHF2 80.7 61 99 71 99 78 92 24 CHF2CF2CHFCF2CHF2 82.6 62 99 72 99 79 92 24 CHF2CF2CF2CF2CH2F 69.8 57 99 67 99 75 91 24 CH3(CF2)4CF3 67.1 51 99 61 99 71 90 24 CH2FCHF(CF2)3CF3 87.4 59 99 69 99 76 91 24 CH2FCF2CHFCF2CF2CF3 92.3 61 99 71 99 78 92 24 CH2FCF2CF2CHFCF2CF3 95.8 62 99 72 99 79 92 24 CH2F(CF2)3CHFCF3 95.4 62 99 72 99 79 92 24 CF2HCH2(CF2)3CF3 88.7 59 99 69 99 77 92 24 CF2HCHFCHFCF2CF2CF3 100.8 63 99 73 99 80 93 24 CF2HCHFCF2CHFCF2CF3 104.9 65 99 75 99 81 93 24 CF2HCHFCF2CF2CHFCF3 106.3 65 99 75 99 81 93 24 CF2HCF2CH2CF2CF2CF3 94 61 99 71 99 78 92 24 CF2HCF2CHFCHFCF2CF3 105.3 65 99 75 99 81 93 24 CF2HCF2CHFCF2CHFCF3 107.3 65 99 75 99 81 93 24 CF2HCF2CF2CH2CF2CF3 97.4 62 99 72 99 79 92 24 CF2HCF2CF2CHFCHFCF3 106.6 65 99 75 99 81 93 24 CF2H(CF2)3CH2CF3 967 62 99 72 99 79 92 24 CF3CH2CHFCF2CF2CF3 89.5 60 99 70 99 77 92 24 CF3CH2CF2CHFCF2CF3 94.1 61 99 71 99 78 92 24 CF3CHFCF2CF2CH2CF3 97.2 62 99 72 99 79 92 24 CF3CF2CF2CH2CHFCF3 89.9 60 99 70 99 77 92 24 CF3CHFCHFCHFCF2CF3 101.6 64 99 74 99 80 93 24 CF3CHFCF2CHFCHFCF3 105.4 65 99 75 99 81 93 24 CF3CHFCF2CH2CF2CF3 94.5 61 99 71 99 78 92 24 CF3CF2CH2CHFCF2CF3 90.2 60 99 70 99 77 92 24 CH2F(CF2)4CF2H 94.9 62 99 72 99 78 92 24 CF2HCHF(CF2)3CF2H 105.8 65 99 75 99 81 93 24 CF2HCF2CHFCF2CF2CF2H 108.5 66 99 76 99 82 93 24 CF3CHFCHFCF3 38.7 47 95 57 99 67 88 20 CF3CF2CF2CH2F 25.7 40 90 50 99 62 87 19 CF3CF2CHFCHF2 37.4 46 95 56 99 67 88 20 CF3CHFCF2CHF2 39.8 47 95 57 99 68 89 20 CF3CF2CH2CHF2 29.1 42 90 52 99 64 87 19 CHF2CF2CF2CHF2 40.1 47 95 57 99 68 89 20 CH2FCF2CF2CH2CF3 50.8 47 99 57 99 67 88 21 CF2HCHFCF2CF2CF3 617 52 99 62 99 71 90 22 CF2HCF2CF2FCF2CF3 65.3 53 99 63 99 72 90 22 CF2HCF2CF2CHFCF3 65.8 53 99 63 99 72 90 22 CF3HCF2CF2CF2CF3 52.6 48 99 58 99 68 89 22 CF3CF2CHFCHFCF3 63.3 52 99 62 99 72 90 23 CF3CHFCF2CHFCF3 64.6 53 99 63 99 12 90 23 CF3CF2CH2CF2CF3 55 49 99 59 99 69 89 22 CF2HCF2CF2CF2CF2H 65.3 53 99 63 99 72 90 23 CF3CF2CHFCHFCF2CF3 88 58 99 68 99 75 91 24 CF3CF2CF2CH2CF2CF3 78.4 54 99 64 99 73 90 24 CF3CHFCF2CF2CHFCF3 914 59 99 69 99 76 91 24 CF3CF2CHFCF2CHFCF3 90 58 99 68 99 76 91 24 CF3CHFCHFCF2CF2CF3 87.6 57 99 67 99 75 91 24 CF3CF2CF2CF2CH2CF3 77.7 54 99 64 99 73 90 24 CF3CF2CF2CF2CHFCHF2 86.8 57 99 67 99 75 91 24 CF3CF2CF2CHFCF2CHF2 89.5 58 99 68 99 76 91 24 CF3CF2CHFCF2CF2CHF2 91.2 59 99 69 99 76 91 24 CF3CHFCF2CF2CF2CHF2 90.9 59 99 69 99 76 91 24 CF3CF2CF2CF2CF2CH2F 75.9 53 99 63 99 72 90 24 CF2HCF2CF2CF2CF2CHF2 90.4 58 99 68 99 76 91 24 CF2HCF2CF2CF2CF2CF3 71.4 50 99 60 99 70 89 24 CF3CHFCF2CF2CF2CF3 71.9 50 99 60 99 70 89 24 CF3CF2CHFCF2CF2CF3 72.2 50 99 60 99 70 89 24 CF2HCF2CF2CF3 21.1 36 90 46 80 54 71 16 CF3CHFCF2CF3 22.5 36 90 46 80 55 72 16 CF2HCF2CF3 −3.14 28 60 38 50 41 47 −5 CF3CHFCF3 −2.99 29 60 39 50 41 47 −5

TABLE 2 245ea azeotropes at 25° C. 245ea Preferred 245ea More Preferred 245ea Most Preferred NBP = 40.0 VP = 0.53 atm Compositions (wt %) Compositions (wt %) Compositions (wt %) Azeo STRUCTURE est. BP (° C.) Upper Lower Upper Lower Upper Lower NBP (±1) CF3CF2CF2CH2CH3 46.3 1 90 10 88 30 69 34 CF3CF2CH2CF2CH3 59.4 1 95 10 93 31 72 35 CF3CF2CHFCHFCH3 61.7 1 95 10 93 31 72 35 CF2CH2CF2CF2CH3 67.2 1 95 10 93 31 72 35 CF3CHFCF2CHFCH3 68 1 95 10 93 31 72 35 CF3CHFCHFCF2CH3 72.9 1 97 10 95 31 74 36 CF3CF2CHFCH2CH2F 70 1 97 10 95 31 74 36 CF3CF2CH2CHFCH2F 75.2 1 97 10 95 31 74 36 CF3CHFCF2CH2CH2F 76.8 1 97 10 95 31 74 36 CF3CHFCH2CF2CH2F 83.1 1 99 10 97 32 75 37 CF3CH2CF2CHFCH2F 84.2 1 99 10 97 32 75 37 CF3CH2CHFCF2CH2F 85.4 1 99 10 97 32 75 37 CF3CHFCHFCHFCH2F 89.1 1 99 10 97 32 75 37 CF3CF2CH2CH2CHF2 72.5 1 97 10 95 31 74 36 CF3CH2CH2CF2CHF2 80.4 1 99 10 97 32 75 37 CF3CH2CF2CH2CHF2 82 1 99 10 97 32 75 37 CF3CHFCHFCH2CHF2 86.5 1 99 10 97 32 75 37 CF3CHFCH2CHFCHF2 87.7 1 99 10 97 32 75 37 CF3CH2CHFCHFCHF2 90.4 1 99 10 97 32 75 38 CF3CH2CH2CHFCF3 72.9 1 97 10 95 31 74 37 CF3CH2CHFCH2CF3 75.7 1 97 10 95 31 74 37 CH2FCF2CF2CF2CH3 65.4 1 95 10 93 31 72 37 CH2FCH2CF2CF2CHF2 79.7 1 99 10 97 32 75 37 CH2FCF2CF2CH2CHF2 87.1 1 99 10 97 32 75 38 CH2FCF2CH2CF2CHF2 87.2 1 99 10 97 32 75 38 CH2FCHFCHFCF2CHF2 92.8 1 99 10 97 32 75 38 CH2FCHFCF2CHFCHF2 95 1 99 10 97 32 75 38 CH2FCF2CHFCHFCHF2 96.6 1 99 10 97 32 75 38 CHF2CF2CF2CHFCH3 69.2 1 95 10 93 31 72 36 CHF2CF2CHFCF2CH3 74.8 1 97 10 95 31 74 36 CHF2CHFCF2CF2CH3 76.3 1 97 10 95 31 74 36 CHF2CF2CHFCH2CHF2 91.9 1 99 10 97 32 75 38 CHF2CHFCF2CH2CHF2 94.6 1 99 10 97 32 75 38 CHF2CF2CH2CHFCHF2 93.6 1 99 10 97 32 75 38 CHF2CHFCHFCHFCHF2 103.4 1 99 10 97 32 75 38 CH2FCHFCF2CF2CH2F 85.8 1 99 10 97 32 75 38 CH2FCF2CHFCF2CH2F 88.1 1 99 10 97 32 75 38 CF3CH2CH2CF3 40.7 1 80 10 78 27 61 34 CF3CHFCH2CHF2 50.8 1 90 10 88 30 69 35 CF3CH2CHFCHF2 53 1 90 10 88 30 69 35 CF3CF2CH2CH2F 37.3 1 70 10 68 25 54 32 CF3CHFCHFCH2F 50.8 1 90 10 88 30 69 35 CF3CH2CF2CH2F 45.8 1 90 10 88 30 69 35 CHF2CH2CF2CHF2 55.7 1 90 10 88 30 69 36 CHF2CHFCHFCHF2 65.1 1 85 10 83 28 65 37 CHF2CF2CHFCH2F 55.3 1 90 10 88 30 69 36 CHF2CHFCF2CH2F 57.5 1 90 10 88 30 69 36 CH2FCF2CF2CH2F 49.2 1 90 10 88 30 69 35 CHF2CF2CF2CH3 35.8 1 70 10 68 25 54 30 CF3CF2CHFCH3 26 1 70 10 68 25 54 23 CF3CHFCF2CH3 32 1 70 10 68 25 54 29 CF3CHFCHFCF2CHFCH2F 120.9 1 99 10 97 32 75 39 CF3CH2CF2CF2CHFCH2F 112.7 1 99 10 97 32 75 39 CF3CF2CHFCH2CF2CH2F 106.9 1 99 10 97 32 75 39 CF3CHFCF2CH2CF2CH2F 111.2 1 99 10 97 32 75 39 CF3CF2CH2CHFCF2CH2F 110.3 1 99 10 97 32 75 39 CF3CHFCHFCHFCF2CH2F 121.8 1 99 10 97 32 75 39 CF3CH2CF2CFHCF2CH2F 114.2 1 99 10 97 32 75 39 CF3CHFCH2CF2CF2CH2F 113.4 1 99 10 97 32 75 39 CF3CH2CHFCF2CF2CH2F 113.1 1 99 10 97 32 75 39 CF3CHFCH2CF2CHFCHF2 120.9 1 99 10 97 32 75 39 CF3CH2CHFCF2CHFCHF2 122.2 1 99 10 97 32 75 39 CF2CF2CH2CH2CF2CHF2 104.6 1 99 10 97 32 75 39 CF3CHFCHFCH2CF2CHF2 117.8 1 99 10 97 32 75 39 CF3CH2CF2CH2CF2CHF2 112.4 1 99 10 97 32 75 39 CF3CHFCH2CHFCF2CHF2 117.3 1 99 10 97 32 75 39 CF3CH2CH2CF2CF2CHF2 107.3 1 99 10 97 32 75 39 CF3CH2CHFCHFCF2CHF2 119.2 1 99 10 97 32 75 39 CF3CF2CF2CF2CH2CH3 71.4 1 90 10 88 30 69 37 CF3CF2CF2CHFCHFCH3 86 1 90 10 88 30 69 38 CF3CF2CHFCF2CHFCH3 93.5 1 99 10 97 32 75 38 CF3CHFCF2CF2CHFCH3 94.9 1 99 10 97 32 75 38 CF3CF2CF2CH2CF2CH3 82.8 1 99 10 97 32 75 38 CF3CF2CHFCHFCF2CH3 97.5 1 99 10 97 32 75 38 CF3CHFCF2CHFCF2CH3 99.6 1 99 10 97 32 75 38 CF3CF2CH2CF2CF2CH3 93 1 99 10 97 32 75 38 CF3CHFCHFCF2CF2CH3 102.3 1 99 10 97 32 75 39 CF3CH2CF2CF2CF2CH3 92.4 1 99 10 97 32 75 39 CHF2CF2CF2CHFCH2CHF2 117.8 1 99 10 97 32 75 39 CHF2CF2CHFCF2CH2CHF2 122.4 1 99 10 97 32 75 39 CHF2CHFCF2CF2CH2CHF2 123.1 1 99 10 97 32 75 39 CF3CF2CHFCH2CHFCHF2 120.4 1 99 10 97 32 75 39 CHF2CF2CHFCHFCHFCHF2 132.1 1 99 10 97 32 75 39 CHF2CHFCF2CHFCHFCHF2 133.5 1 99 10 97 32 75 39 CGF2CF2CH2CF2CHFCHF2 124.9 1 99 10 97 32 75 39 CHF2CF2CHFCH2CF2CHF2 123.1 1 99 10 97 32 75 39 CHF2CF2CF2CF2CH2CH2F 104.8 1 99 10 97 32 75 39 CHF2CF2CF2CHFCHFCH2F 118.7 1 99 10 97 32 75 39 CHF2CF2CHFCF2CHFCH2F 122.9 1 99 10 97 32 75 39 CHF2CHFCF2CF2CHFCH2F 121.8 1 99 10 97 32 75 39 CHF2CF2CF2CH2CF2CH2F 114.1 1 99 10 97 32 75 39 CHF2CF2CHFCHFCF2CH2F 125.4 1 99 10 97 32 75 39 CHF2CHFCF2CHFCF2CH2F 125 1 99 10 97 32 75 39 CHF2CF2CH2CF2CF2CH2F 117.5 1 99 10 97 32 75 39 CHF2CHFCHFCF2CF2CH2F 124.2 1 99 10 97 32 75 39 CHF2CH2CF2CF2CF2CH2F 112.2 1 99 10 97 32 75 39 CF2HCF2CF2CF2CHFCH3 94.4 1 99 10 97 32 75 39 CF2HCF2CF2CHFCF2CH3 100.8 1 99 10 97 32 75 39 CHF2CF2CHFCF2CF2CH3 104.2 1 99 10 97 32 75 39 CHF2CHFCF2CF2CF2CH3 101.4 1 99 10 97 32 75 39 CH2FCF2CF2CF2CF2CH3 90.6 1 99 10 97 32 75 39 CH2FCF2CF2CF2CHFCH2F 110.9 1 99 10 97 32 75 39 CH2FCF2CF2CHFCF2CH2F 115.9 1 99 10 97 32 75 39 CF3CH2CH2CHFCF2CF3 96.7 1 99 10 97 32 75 39 CF3CH2CH2CF2CHFCF3 104.4 1 99 10 97 32 75 39 CF3CF2CH2CHFCH2CF3 100.7 1 99 10 97 32 75 39 CF3CHFCHFCHFCH2CF3 115.5 1 99 10 97 32 75 39 CF3CH2CF2CHFCH2CF3 111.4 1 99 10 97 32 75 39 CF3CHFCH2CF2CH2CF3 108.4 1 99 10 97 32 75 39 CF3CHFCH2CH2CF2CF3 97.1 1 99 10 97 32 75 39 CF3CHFCHFCH2CHFCF3 112 1 99 10 97 32 75 39 CF3CF2CF2CH2CH2CHF2 95.9 1 99 10 97 32 75 39 CF3CF2CHFCHFCH2CHF2 111.2 1 99 10 97 32 75 39 CF3CHFCF2CHFCH2CHF2 116.6 1 99 10 97 32 75 39 CF3CF2CH2CF2CH2CHF2 107.9 1 99 10 97 32 75 39 CF3CHFCHFCF2CH2CHF2 120.5 1 99 10 97 32 75 39 CF3CH2CF2CF2CH2CHF2 114 1 99 10 97 32 75 39 CF3CF2CHFCH2CHFCHF2 111.5 1 99 10 97 32 75 39 CF3CHFCF2CH2CHFCHF2 117.4 1 99 10 97 32 75 39 CF3CF2CH2CHFCHFCHF2 115.4 1 99 10 97 32 75 39 CF3CHFCHFCHFCHFCHF2 128.5 1 99 10 97 32 75 39 CF3CH2CF2CHFCHFCHF2 122.7 1 99 10 97 32 75 39 CF3CF2CF2CHFCH2CH2F 94.3 1 99 10 97 32 75 39 CF3CF2CHFCF2CH2CH2F 102.3 1 99 10 97 32 75 39 CF3CHFCF2CF2CH2CH2F 105.3 1 99 10 97 32 75 39 CF3CF2CF2CH2CHFCH2F 98.6 1 99 10 97 32 75 39 CF3CF2CHFCHFCHFCH2F 113.8 1 99 10 97 32 75 39 CF3CHFCF2CHFCHFCH2F 117.5 1 99 10 97 32 75 39 CF3CF2CH2CF2CHFCH2F 110 1 99 10 97 32 75 39 CH3CHFCF2CF2CF3 50.2 1 90 10 88 30 69 35 CH3CF2CFHCF2CF3 57.5 1 90 10 88 30 69 35 CH3CF2CF2CHFCF3 60.9 1 95 10 93 31 72 36 CH2FCH2CF2CF2CF3 60.7 1 95 10 93 31 72 36 CH2FCHFCHFCF2CF3 75.5 1 95 10 93 31 72 37 CH2FCHFCF2CHFCF3 80.1 1 97 10 95 31 74 38 CH2FCF2CH2CF2CF3 71.6 1 95 10 93 31 72 37 CH2FCF2CHFCHFCF3 83.5 1 99 10 97 32 75 38 CH2FCF2CF2CH2CF3 76.1 1 95 10 93 31 72 37 CF2HCH2CHFCF2CF3 74.6 1 95 10 93 31 72 38 CF2HCH2CF2CHFCF3 79.7 1 95 10 93 31 72 38 CF2HCHFCH2CF2CF3 77.9 1 95 10 93 31 72 38 CF2HCHFCHFCHFCF3 90.2 1 99 10 97 32 75 38 CF2HCHFCF2CH2CF3 83.5 1 99 10 97 32 75 38 CF2HCF2CH2CFHCF3 82 1 99 10 97 32 75 38 CF2HCF2CHFCH2CF3 82.6 1 99 10 97 32 75 38 CF3CH2CH2CF2CF3 64.8 1 95 10 93 31 72 37 CF3CH2CHFCHFCF3 77.2 1 95 10 93 31 72 38 CF3CH2CF2CH2CF3 71 1 95 10 93 31 72 37 CF3CHFCH2CHFCF3 76.2 1 95 10 93 31 72 38 CH2FCF2CHFCF2CF2H 85.4 1 99 10 97 32 75 38 CH2FCF2CF2CHFCF2H 85.2 1 99 10 97 32 75 38 CH2FCHFCF2CF2CF2H 81.3 1 99 10 97 32 75 38 CH3CF2CF2CF2CF2H 60.9 1 95 10 93 31 72 36 CF2HCF2CHFCH2CF3 82.6 1 99 10 97 32 75 38 CF2HCHFCHFCF2CF2H 93.8 1 99 10 97 32 75 39 CF2HCHFCF2CHFCF2H 94.3 1 99 10 97 32 75 39 CF2HCF2CH2CF2CF2H 86.1 1 99 10 97 32 75 38 CH2FCF2CF2CF2CH2F 74.3 1 95 10 93 31 72 37 CF3CF2CF2CH2CH2CF3 88.3 1 99 10 97 32 75 38 CF3CF2CHFCHFCH2CF3 101.9 1 99 10 97 32 75 39 CF3CHFCF2CHFCH2CF3 107.3 1 99 10 97 32 75 39 CF3CF2CH2CF2CH2CF3 96.9 1 99 10 97 32 75 39 CF3CHFCHFCF2CH2CF3 109.5 1 99 10 97 32 75 39 CF3CH2CF2CF2CH2CF3 103 1 99 10 97 32 75 39 CF3CHFCH2CHFCF2CF3 100 1 99 10 97 32 75 39 CF3CHFCH2CF2CHFCF3 10.6 1 99 10 97 32 75 39 CF3CHFCHFCH2CF2CF3 102.2 1 99 10 97 32 75 39 CF3CHFCHFCHFCHFCF3 115.3 1 99 10 97 32 75 39 CF3CF2CH2CH2CF2CF3 89 1 99 10 97 32 75 38 CF3CF2CF2CHFCH2CHF2 98.8 1 99 10 97 32 75 39 CF3CF2CHFCF2CH2CHF2 105.1 1 99 10 97 32 75 39 CF3CHFCF2CF2CHFCHF2 108.2 1 99 10 97 32 75 39 CF3CF2CF2CH2CHFCHF2 101.4 1 99 10 97 32 75 39 CF3CF2CHFCHFCHFCHF2 114.8 1 99 10 97 32 75 39 CF3CHFCF2CHFCHFCHF2 118.6 1 99 10 97 32 75 39 CF3CF2CH2CF2CHFCHF2 109.4 1 99 10 97 32 75 39 CF3CHFCHFCF2CHFCHF2 120.3 1 99 10 97 32 75 39 CF3CH2CF2CF2CHFCHF2 112.1 1 99 10 97 32 75 39 CF3CF2CHFCH2CF2CHF2 105.8 1 99 10 97 32 75 39 CF3CHFCF2CH2CF2CHF2 110.1 1 99 10 97 32 75 39 CF3CF2CH2CHFCF2CHF2 107.5 1 99 10 97 32 75 39 CF3CHFCHFCHFCF2CHF2 118.9 1 99 10 97 32 75 39 CF3CH2CF2CHFCF2CHF2 111.4 1 99 10 97 32 75 39 CF3CHFCH2CF2CF2CHF2 108.9 1 99 10 97 32 75 39 CF3CH2CHFCF2CF2CHF2 108.5 1 99 10 97 32 75 39 CF3CF2CF2CF2CH2CH2F 85.8 1 99 10 97 32 75 39 CF3CF2CF2CHFCHFCH2F 99.7 1 99 10 97 32 75 39 CF3CF2CHFCF2CHFCH2F 105.6 1 99 10 97 32 75 39 CF3CHFCF2CF2CHFCH2F 106.9 1 99 10 97 32 75 39 CF3CF2CF2CH2CF2CH2F 95.1 1 99 10 97 32 75 39 CF3CF2CHFCHFCF2CH2F 108.1 1 99 10 97 32 75 39 CF3CHFCF2CHFCF2CH2F 110.1 1 99 10 97 32 75 39 CF3CF2CH2CF2CF2CH2F 101.9 1 99 10 97 32 75 39 CF3CHFCHFCF2CF2CH2F 111.4 1 99 10 97 32 75 39 CHF2CF2CHFCF2CF2CH2F 101.2 1 99 10 97 32 75 39 CF3CF2CF2CF2CHFCH3 75.4 1 99 10 97 32 75 37 CF3CF2CF2CHFCF2CH3 81.8 1 99 10 97 32 75 38 CF3CF2CHFCF2CF2CH3 86.9 1 99 10 97 32 75 38 CF3CHFCF2CF2CF2CH3 86.6 1 99 10 97 32 75 38 CHF2CF2CF2CHFCHFCHF2 119.8 1 99 10 97 32 75 39 CHF2CF2CHFCF2CHFCHF2 122.2 1 99 10 97 32 75 39 CHF2CHFCF2CF2CHFCHF2 121.2 1 99 10 97 32 75 39 CHF2CF2CF2CH2CF2CHF2 113 1 99 10 97 32 75 39 CHF2CF2CHFCHFCF2CHF2 122.6 1 99 10 97 32 75 39 CHF2CH2CF2CF2CF2CHF2 107.7 1 99 10 97 32 75 39 CHF2CF2CF2CF2CHFCH2F 106.4 1 99 10 97 32 75 39 CHF2CF2CF2CHFCF2CH2F 111.4 1 99 10 97 32 75 39 CHF2CF2CHFCF2CF2CH2F 113.1 1 99 10 97 32 75 39 CHF2CHFCF2CF2CF2CH2F 110.3 1 99 10 97 32 75 39 CH2FCF2CF2CF2CF2CH2F 99.4 1 99 10 97 32 75 39 CHFCF2CF2CF2CF2CH3 86.1 1 99 10 97 32 75 38 CH3CF2CF2CF3 16.8 1 50 10 48 20 39 15 CH2FCHFCF2CF3 38 1 70 10 68 25 54 34 CH2FCF2CHFCF3 42.6 1 75 10 73 26 57 34 CH2FCF2CH2CF3 44.7 1 75 10 73 26 57 34 CF2HCH2CF2CF3 40.2 1 75 10 73 26 57 34 CF2HCHFCHFCF3 51.9 1 75 10 73 26 57 35 CF3CH2CHFCF3 41.5 1 75 10 73 26 57 34 CH2FCF2CF2CF2H 44.7 1 75 10 73 26 57 34 CF2HCHFCF2CF2H 54.7 1 75 10 73 26 57 35 CF3CF2CHFCH2CF3 65.3 1 95 10 93 31 72 36 CF3CH2CF2CHFCF3 68.6 1 95 10 93 31 72 36 CF3CHFCH2CF2CF3 66.5 1 95 10 93 31 72 36 CF3CHFCFHCFHCF3 77 1 95 10 93 31 72 37 CF3CH2CF2CF2CHF2 71.6 1 95 10 93 31 72 37 CF3CHFCHFCF2CHF2 80.6 1 99 10 97 32 75 38 CF3CF2CH2CF2CHF2 70.5 1 95 10 93 31 72 37 CF3CHFCF2CHFCHF2 79.5 1 95 10 93 31 72 38 CF3CF2CHFCHFCHF2 76.5 1 95 10 93 31 72 38 CF3CF2CF2CH2CHF2 63.6 1 90 10 88 30 69 37 CF3CF2CF2CHFCH2F 62.3 1 90 10 88 30 69 37 CF3CF2CHFCF2CH2F 68.1 1 90 10 88 30 69 37 CF3CHFCF2CF2CH2F 70.3 1 90 10 88 30 69 37 CF3CF2CF2CF2CH3 41.9 1 80 10 78 27 61 34 CHF2CF2CF2CHFCHF2 80.7 1 99 10 97 32 75 38 CHF2CF2CHFCF2CHF2 82.6 1 99 10 97 32 75 38 CHF2CF2CF2CF2CH2F 69.8 1 95 10 93 31 72 37 CH3(CF2)4CF3 67.1 1 95 10 93 31 72 37 CH2FCHF(CF2)3CF3 87.4 1 99 10 97 32 75 38 CH2FCF2CHFCF2CF2CF3 92.3 1 99 10 97 32 75 39 CH2FCF2CF2CHFCF2CF3 95.8 1 99 10 97 32 75 39 CH2F(CF2)3CHFCF3 95.4 1 99 10 97 32 75 39 CF2HCH2(CF2)3CF3 88.7 1 99 10 97 32 75 38 CF2HCHFCHFCF2CF2CF3 100.8 1 99 10 97 32 75 39 CF2HCHFCF2CHFCF2CF3 104.9 1 99 10 97 32 75 39 CF2HCHFCF2CF2CHFCF3 106.3 1 99 10 97 32 75 39 CF2HCF2CH2CF2CF2CF3 94 1 99 10 97 32 75 39 CF2HCF2CHFCHFCF2CF3 105.3 1 99 10 97 32 75 39 CF2HCF2CHFCF2CHFCF3 107.3 1 99 10 97 32 75 39 CF2HCF2CF2CH2CF2CF3 97.4 1 99 10 97 32 75 39 CF2HCF2CF2CHFCHFCF3 106.6 1 99 10 97 32 75 39 CF2H(CF2)3CH2CF3 96.7 1 99 10 97 32 75 39 CF3CH2CHFCF2CF2CF3 89.5 1 99 10 97 32 75 39 CF3CH2CF2CHFCF2CF3 94.1 1 99 10 97 32 75 39 CF3CHFCF2CF2CH2CF3 97.2 1 99 10 97 32 75 39 CF3CF2CF2CH2CHFCF3 89.9 1 99 10 97 32 75 39 CF3CHFCHFCHFCF2CF3 101.6 1 99 10 97 32 75 39 CF3CHFCF2CHFCHFCF3 105.4 1 99 10 97 32 75 39 CF3CHFCF2CH2CF2CF3 94.5 1 99 10 97 32 75 39 CF3CF2CH2CHFCF2CF3 90.2 1 99 10 97 32 75 39 CH2F(CF2)4CF2H 94.9 1 99 10 97 32 75 39 CF2HCHF(CF2)3CF2H 105.8 1 99 10 97 32 75 39 CF2HCF2CHFCF2CF2CF2H 108.5 1 99 10 97 32 75 39 CF3CHFCHFCF3 38.7 1 70 10 68 25 54 33 CF3CF2CF2CH2F 25.7 1 60 10 58 22 46 22 CF3CF2CHFCHF2 37.4 1 70 10 68 25 54 32 CF3CHFCF2CHF2 39.8 1 70 10 68 25 54 34 CF3CF2CH2CHF2 29.1 1 70 10 68 25 54 26 CHF2CF2CF2CHF2 40.1 1 70 10 68 25 54 34 CH2FCF2CF2CH2CF3 50.8 1 90 10 88 30 69 35 CF2HCHFCF2CF2CF3 61.7 1 95 10 93 31 72 36 CF2HCF2CHFCF2CF3 65.3 1 95 10 93 31 72 36 CF2HCF2CF2CHFCF3 65.8 1 95 10 93 31 72 36 CF3CH2CF2CF2CF3 52.6 1 95 10 93 31 72 35 CF3CF2CHFCHFCF3 63.3 1 95 10 93 31 72 36 CF3CHFCF2CHFCF3 64.6 1 95 10 93 31 72 36 CF3CF2CH2CF2CF3 55 1 95 10 93 31 72 35 CF2HCF2CF2CF2CF2H 65.3 1 95 10 93 31 72 36 CF3CF2CHFCHFCF2CF3 88 1 99 10 97 32 75 39 CF3CF2CF2CH2CF2CF3 78.4 1 99 10 97 32 75 39 CF3CHFCF2CF2CHFCF3 91.4 1 99 10 97 32 75 39 CF3CF2CHFCF2CHFCF3 90 1 99 10 97 32 75 39 CF3CHFCHFCF2CF2CF3 87.6 1 99 10 97 32 75 39 CF3CF2CF2CF2CH2CF3 77.7 1 99 10 97 32 75 39 CF3CF2CF2CF2CHFCHF2 86.8 1 99 10 97 32 75 39 CF3CF2CF2CHFCF2CHF2 89.5 1 99 10 97 32 75 39 CF3CF2CHFCF2CF2CHF2 91.2 1 99 10 97 32 75 39 CF3CHFCF2CF2CF2CHF2 90.9 1 99 10 97 32 75 39 CF3CF2CF2CF2CF2CH2F 75.9 1 99 10 97 32 75 37 CF2HCF2CF2CF2CF2CHF2 90.4 1 99 10 97 32 75 39 CF2HCF2CF2CF2CF2CF3 71.4 1 95 10 93 31 72 37 CF3CHFCF2CF2CF2CF3 71.9 1 95 10 93 31 72 37 CF3CF2CHFCF2CF2CF3 72.2 1 95 10 93 31 72 37 CF2HCF2CF2CF3 21.1 20  70 30 68 40 59 19 CF3CHFCF2CF3 22.5 20  70 30 68 40 59 20 CF2HCF2CF3 −3.14 10  50 20 48 27 41 −2 CF3CHFCF3 −2.99 10  50 20 48 27 41 −2

TABLE 3 245eb azeotropes 245eb Preferred 245eb More Preferred 245eb Most Preferred Azeo NBP (22.7° C.) VP = 1.08 atm Composition (wt. %) Composition (wt. %) Composition (wt. %) BP (° C.) STRUCTURE est. BP (° C.) Lower Upper Lower Upper Lower Upper (±1) CF3CF2CF2CH2CH3 46.3 1 99 10 99 32 77 17 CF3CF2CF2CF2CH3 59.4 1 99 10 99 32 77 19 CF3CF2CHFCHFCH3 61.7 1 99 10 99 32 77 20 CF2CH2CF2CF2CH3 67.2 1 99 10 99 32 77 20 CF3CHFCF2CHFCH3 68 1 99 10 99 32 77 20 CF3CHFCHFCF2CH3 72.9 1 99 10 99 32 77 21 CF3CH2CHFCH2CH2F 70 1 99 10 99 32 77 21 CF3CF2CH2CHFCH2F 75.2 1 99 10 99 32 77 21 CF3CHFCF2CH2CH2F 76.8 1 99 10 99 32 77 21 CF3CHFCH2CF2CH2F 83.1 1 99 10 99 32 77 21 CF3CH2CF2CHFCH2F 84.2 1 99 10 99 32 77 21 CF3CH2CHFCF2CH2F 85.4 1 99 10 99 32 77 21 CF3CHFCHFCHFCH2F 89.1 1 99 10 99 32 77 21 CF3CF2CH2CH2CHF2 72.5 1 99 10 99 32 77 21 CF3CH2CH2CF2CHF2 80.4 1 99 10 99 32 77 21 CF3CH2CF2CH2CHF2 82 1 99 10 99 32 77 21 CF3CHFCHFCH2CHF2 86.5 1 99 10 99 32 77 21 CF3CHFCH2CHFCHF2 87.7 1 99 10 99 32 77 21 CF3CH2CHFCHFCHF2 90.4 1 99 10 99 32 77 21 CF3CH2CH2CHFCF3 72.9 1 99 10 99 32 77 21 CF3CH2CHFCH2CF3 75.7 1 99 10 99 32 77 21 CH2FCF2CF2CF2CH3 65.4 1 99 10 99 32 77 21 CH2FCH2CF2CF2CHF2 79.7 1 99 10 99 32 77 21 CH2FCF2CF2CH2CHF2 87.1 1 99 10 99 32 77 21 CH2FCF2CH2CF2CHF2 87.2 1 99 10 99 32 77 21 CH2FCHFCHFCF2CHF2 92.8 1 99 10 99 32 77 21 CH2FCHFCF2CHFCHF2 95 1 99 10 99 32 77 21 CH2FCF2CHFCHFCHF2 96.6 1 99 10 99 32 77 21 CHF2CF2CF2CHFCH3 69.2 1 99 10 99 32 77 20 CHF2CF2CHFCF2CH3 74.8 1 99 10 99 32 77 21 CHF2CHFCF2CF2CH3 76.3 1 99 10 99 32 77 21 CHF2CF2CHFCH2CHF2 91.9 1 99 10 99 32 77 21 CHF2CHFCF2CH2CHF2 94.6 1 99 10 99 32 77 21 CHF2CF2CH2CHFCHF2 93.6 1 99 10 99 32 77 21 CHF2CHFCHFCHFCHF2 103.4 1 99 10 99 32 77 21 CH2FCHFCF2CF2CH2F 85.8 1 99 10 99 32 77 21 CH2FCF2CHFCF2CH2F 88.1 1 99 10 99 32 77 21 CF3CH2CH2CF3 40.7 1 99 10 99 32 77 17 CH3CHFCH2CHF2 50.8 1 99 10 99 32 77 18 CF3CH2CHFCHF2 53 1 99 10 99 32 77 18 CF3CF2CH2CH2F 37.3 1 99 10 99 32 77 17 CF3CHFCHFCH2F 50.8 1 99 10 99 32 77 18 CF3CH2CF2CH2F 45.8 1 99 10 99 32 77 17 CHF2CH2CF2CHF2 55.7 1 99 10 99 32 77 19 CHF2CHFCHFCHF2 65.1 1 99 10 99 32 77 20 CHF2CF2CHFCH2F 55.3 1 99 10 99 32 77 19 CHF2CHFCF2CH2F 57.5 1 99 10 99 32 77 19 CH2FCF2CF2CH2F 49.2 1 99 10 99 32 77 18 CHF2CF2CF2CH3 35.8 1 99 10 99 32 77 17 CF3CF2CHFCH3 26 1 95 10 95 31 74 16 CF3CHFCF2CH3 32 1 95 10 95 31 74 17 CF3CHFCHFCF2CHFCH2F 120.9 1 99 10 99 32 77 21 CF3CH2CF2CF2CHFCH2F 112.7 1 99 10 99 32 77 21 CF3CF2CHFCH2CF2CH2F 106.9 1 99 10 99 32 77 21 CF3CHFCF2CH2CF2CH2F 111.2 1 99 10 99 32 77 21 CF3CF2CH2CHFCF2CH2F 110.3 1 99 10 99 32 77 21 CF3CHFCHFCHFCF2CH2F 121.8 1 99 10 99 32 77 21 CF3CH2CF2CFHCF2CH2F 114.2 1 99 10 99 32 77 21 CF3CHFCH2CF2CF2CH2F 113.4 1 99 10 99 32 77 21 CF3CH2CHFCF2CF2CH2F 113.1 1 99 10 99 32 77 21 CF3CHFCH2CF2CHFCHF2 120.9 1 99 10 99 32 77 21 CF3CH2CHFCF2CHFCHF2 122.2 1 99 10 99 32 77 21 CF2CF2CH2CH2CF2CHF2 104.6 1 99 10 99 32 77 21 CF3CHFCHFCH2CF2CHF2 117.8 1 99 10 99 32 77 21 CF3CH2CF2CH2CF2CHF2 112.4 1 99 10 99 32 77 21 CF3CHFCH2CHFCF2CHF2 117.3 1 99 10 99 32 77 21 CF3CH2CH2CF2CF2CHF2 107.3 1 99 10 99 32 77 21 CF3CH2CHFCHFCF2CHF2 119.2 1 99 10 99 32 77 21 CF3CF2CF2CF2CH2CH3 71.4 1 99 10 99 32 77 21 CF3CF2CF2CHFCHFCH3 86 1 99 10 99 32 77 21 CF3CF2CHFCF2CHFCH3 93.5 1 99 10 99 32 77 21 CF3CHFCF2CF2CHFCH3 94.9 1 99 10 99 32 77 21 CF3CF2CF2CH2CF2CH3 82.8 1 99 10 99 32 77 21 CF3CF2CHFCHCF2CH3 97.5 1 99 10 99 32 77 21 CF3CHFCF2CHFCF2CH3 99.6 1 99 10 99 32 77 21 CF3CF2CH2CF2CF2CH3 93 1 99 10 99 32 77 21 CF3CHFCHFCF2CF2CH3 102.3 1 99 10 99 32 77 21 CF3CH2CF2CF2CF2CH3 92.4 1 99 10 99 32 77 21 CHF2CF2CF2CHFCH2CHF2 117.8 1 99 10 99 32 77 21 CHF2CF2CHFCF2CH2CHF2 122.4 1 99 10 99 32 77 21 CHF2CHFCF2CF2CH2CHF2 123.1 1 99 10 99 32 77 21 CF3CF2CHFCH2CHFCHF2 120.4 1 99 10 99 32 77 21 CHF2CF2CHFCHFCHFCHF2 132.1 1 99 10 99 32 77 21 CHF2CHFCF2CHFCHFCHF2 133.5 1 99 10 99 32 77 21 CGF2CF2CH2CF2CHFCHF2 124.9 1 99 10 99 32 77 21 CHF2CF2CHFCH2CF2CHF2 123.1 1 99 10 99 32 77 21 CHF2CF2CF2CF2CH2CH2F 104.8 1 99 10 99 32 77 21 CHF2CF2CF2CHFCHFCH2F 118.7 1 99 10 99 32 77 21 CHF2CF2CHFCF2CHFCH2F 122.9 1 99 10 99 32 77 21 CHF2CHFCF2CF2CHFCH2F 121.8 1 99 10 99 32 77 21 CHF2CF2CF2CH2CF2CH2F 114.1 1 99 10 99 32 77 21 CHF2CF2CHFCHFCF2CH2F 125.4 1 99 10 99 32 77 21 CHF2CHFCF2CHFCF2CH2F 125 1 99 10 99 32 77 21 CHF2CF2CH2CF2CF2CH2F 117.5 1 99 10 99 32 77 21 CHF2CHFCHFCF2CF2CH2F 124.2 1 99 10 99 32 77 21 CHF2CH2CF2CF2CF2CH2F 112.2 1 99 10 99 32 77 21 CF2HCF2CF2CF2CHFCH3 94.4 1 99 10 99 32 77 21 CF2HCF2CF2CHFCF2CH3 100.8 1 99 10 99 32 77 21 CHF2CF2CHFCF2CF2CH3 104.2 1 99 10 99 32 77 21 CHF2CHFCF2CF2CF2CH3 101.4 1 99 10 99 32 77 21 CH2FCF2CF2CF2CF2CH3 90.6 1 99 10 99 32 77 21 CH2FCF2CF2CF2CHFCH2F 110.9 1 99 10 99 32 77 21 CH2FCF2CF2CHFCF2CH2F 115.9 1 99 10 99 32 77 21 CH3CH2CH2CHFCF2CF3 96.7 1 99 10 99 32 77 21 CF3CH2CH2CF2CHFCF3 104.4 1 99 10 99 32 77 21 CF3CF2CH2CHFCH2CF3 100.7 1 99 10 99 32 77 21 CF3CHFCHFCHFCH2CF3 115.5 1 99 10 99 32 77 21 CF3CH2CF2CHFCH2CF3 111.4 1 99 10 99 32 77 21 CF3CHFCH2CF2CH2CF3 108.4 1 99 10 99 32 77 21 CF3CHFCH2CH2CF2CF3 97.1 1 99 10 99 32 77 21 CF3CHFCHFCH2CHFCF3 112 1 99 10 99 32 77 21 CF3CF2CF2CH2CH2CHF2 95.9 1 99 10 99 32 77 21 CF3CF2CHFCHFCH2CHF2 111.2 1 99 10 99 32 77 21 CF3CHFCF2CHFCH2CHF2 116.6 1 99 10 99 32 77 21 CF3CF2CH2CF2CH2CHF2 107.9 1 99 10 99 32 77 21 CF3CHFCHFCF2CH2CHF2 120.5 1 99 10 99 32 77 21 CF3CH2CF2CF2CH2CHF2 114 1 99 10 99 32 77 21 CF3CF2CHFCH2CHFCHF2 11.5 1 99 10 99 32 77 21 CF3CHFCF2CH2CHFCHF2 117.4 1 99 10 99 32 77 21 CF3CF2CH2CHFCHFCHF2 115.4 1 99 10 99 32 77 21 CF3CHFCHFCHFCHFCHF2 128.5 1 99 10 99 32 77 21 CF3CH2CF2CHFCHFCHF2 122.7 1 99 10 99 32 77 21 CF3CF2CF2CHFCH2CH2F 94.3 1 99 10 99 32 77 21 CF3CF2CHFCF2CH2CH2F 102.3 1 99 10 99 32 77 21 CF3CHFCF2CF2CH2CH2F 105.3 1 99 10 99 32 77 21 CF3CF2CF2CH2CHFCH2F 98.6 1 99 10 99 32 77 21 CF3CF2CHFCHFCHFCH2F 113.8 1 99 10 99 32 77 21 CF3CHFCF2CHFCHFCH2F 117.5 1 99 10 99 32 77 21 CF3CF2CH2CF2CHFCH2F 110 1 99 10 99 32 77 21 CH3CHFCF2CF2CF3 50.2 1 99 10 99 32 77 19 CH3CF2CFHCF2CF3 57.5 1 99 10 99 32 77 19 CH3CF2CF2CHFCF3 60.9 1 99 10 99 32 77 20 CH2FCH2CF2CF2CF3 60.7 1 99 10 99 32 77 20 CH2FCHFCHFCF2CF3 75.5 1 99 10 99 32 77 21 CH2FCHFCF2CHFCF3 80.1 1 99 10 99 32 77 21 CH2FCF2CH2CF2CF3 71.6 1 99 10 99 32 77 21 CH2FCF2CHFCHFCF3 83.5 1 99 10 99 32 77 21 CH2FCF2CF2CH2CF3 76.1 1 99 10 99 32 77 21 CF2HCH2CHFCF2CF3 74.6 1 99 10 99 32 77 21 CF2HCH2CF2CHFCF3 79.7 1 99 10 99 32 77 21 CF2HCHFCH2CF2CF3 77.9 1 99 10 99 32 77 21 CF2HCHFCHFCHFCF3 90.2 1 99 10 99 32 77 21 CF2HCHFCF2CH2CF3 83.5 1 99 10 99 32 77 21 CF2HCF2CH2CFHCF3 82 1 99 10 99 32 77 21 CF2HCF2CHFCH2CF3 82.6 1 99 10 99 32 77 21 CF3CH2CH2CF2CF3 64.8 1 99 10 99 32 77 21 CF3CH2CHFCHFCF3 77.2 1 99 10 99 32 77 21 CF3CH2CF2CH2CF3 71 1 99 10 99 32 77 21 CF3CHFCH2CHFCF3 76.2 1 99 10 99 32 77 21 CH2FCF2CHFCF2CF2H 85.4 1 99 10 99 32 77 21 CH2FCF2CF2CHFCF2H 85.2 1 99 10 99 32 77 21 CH2FCHFCF2CF2CF2H 81.3 1 99 10 99 32 77 21 CH3CF2CF2CF2CF2H 60.9 1 99 10 99 32 77 20 CF2HCH2CF2CF2CF2H 82.6 1 99 10 99 32 77 21 CF2HCHFCHFCF2CF2H 93.8 1 99 10 99 32 77 21 CF2HCHFCF2CHFCF2H 94.3 1 99 10 99 32 77 21 CF2HCF2CH2CF2CF2H 86.1 1 99 10 99 32 77 21 CH2FCF2CF2CF2CH2F 74.3 1 99 10 99 32 77 21 CF3CF2CF2CH2CH2CF3 88.3 1 99 10 99 32 77 21 CF3CF2CHFCHFCH2CF3 101.9 1 99 10 99 32 77 21 CF3CHFCF2CHFCH2CF3 107.3 1 99 10 99 32 77 21 CF3CF2CH2CF2CH2CF3 96.9 1 99 10 99 32 77 21 CF3CHFCHFCF2CH2CF3 109.5 1 99 10 99 32 77 21 CF3CH2CF2CF2CH2CF3 103 1 99 10 99 32 77 21 CF3CHFCH2CHFCF2CF3 100 1 99 10 99 32 77 21 CF3CHFCH2CF2CHFCF3 10.6 1 99 10 99 32 77 21 CF3CHFCHFCH2CF2CF3 102.2 1 99 10 99 32 77 21 CF3CHFCHFCHFCF3 115.3 1 99 10 99 32 77 21 CF3CF2CH2CH2CF2CF3 89 1 99 10 99 32 77 21 CF3CF2CF2CHFCH2CHF2 98.8 1 99 10 99 32 77 21 CF3CF2CHFCF2CH2CHF2 105.1 1 99 10 99 32 77 21 CF3CHFCF2CF2CHFCHF2 108.2 1 99 10 99 32 77 21 CF3CF2CF2CH2CHFCHF2 101.4 1 99 10 99 32 77 21 CF3CF2CHFCHFCHFCHF2 114.8 1 99 10 99 32 77 21 CF3CHFCF2CHFCHFCHF2 118.6 1 99 10 99 32 77 21 CH3CF2CH2CF2CHFCHF2 109.4 1 99 10 99 32 77 21 CF3CHFCHFCF2CHFCHF2 120.3 1 99 10 99 32 77 21 CF3CH2CF2CF2CHFCHF2 112.1 1 99 10 99 32 77 21 CF3CF2CHFCH2CF2CHF2 105.8 1 99 10 99 32 77 21 CF3CHFCF2CH2CF2CHF2 110.1 1 99 10 99 32 77 21 CF3CF2CH2CHFCF2CHF2 107.5 1 99 10 99 32 77 21 CF3CHFCHFCHFCF2CHF2 118.9 1 99 10 99 32 77 21 CF3CH2CF2CHFCF2CHF2 111.4 1 99 10 99 32 77 21 CF3CHFCH2CF2CF2CHF2 108.9 1 99 10 99 32 77 21 CF3CH2CHFCF2CF2CHF2 108.5 1 99 10 99 32 77 21 CF3CF2CF2CF2CH2CH2F 85.8 1 99 10 99 32 77 21 CF3CF2CF2CHFCHFCH2F 99.7 1 99 10 99 32 77 21 CF3CF2CHFCF2CHFCH2F 105.6 1 99 10 99 32 77 21 CF3CHFCF2CF2CHFCH2F 106.9 1 99 10 99 32 77 21 CF3CF2CF2CH2CF2CH2F 95.1 1 99 10 99 32 77 21 CF3CF2CHFCHFCF2CH2F 108.1 1 99 10 99 32 77 21 CF3CHFCF2CHFCF2CH2F 110.1 1 99 10 99 32 77 21 CF3CH2CH2CF2CF2CH2F 101.9 1 99 10 99 32 77 21 CF3CHFCHFCF2CF2CH2F 111.4 1 99 10 99 32 77 21 CHF2CF2CHFCF2CF2CH2F 101.2 1 99 10 99 32 77 21 CF3CF2CF2CF2CHFCH3 75.4 1 99 10 99 32 77 21 CF3CF2CF2CHFCF2CH3 81.8 1 99 10 99 32 77 21 CF3CH2CHFCF2CF2CH3 86.9 1 99 10 99 32 77 21 CF3CHFCF2CF2CF2CH3 86.6 1 99 10 99 32 77 21 CHF2CH2CF2CHFCHFCHF2 119.8 1 99 10 99 32 77 21 CHF2CF2CHFCF2CHFCHF2 122.2 1 99 10 99 32 77 21 CHF2CHFCF2CF2CHFCHF2 121.2 1 99 10 99 32 77 21 CHF2CF2CF2CH2CF2CHF2 113 1 99 10 99 32 77 21 CHF2CF2CHFCHFCF2CHF2 122.6 1 99 10 99 32 77 21 CHF2CH2CF2CF2CF2CHF2 107.7 1 99 10 99 32 77 21 CHF2CF2CF2CF2CHFCH2F 106.4 1 99 10 99 32 77 21 CHF2CF2CF2CHFCF2CH2F 111.4 1 99 10 99 32 77 21 CHF2CF2CHFCF2CF2CH2F 113.1 1 99 10 99 32 77 21 CHF2CHFCF2CF2CF2CH2F 110.3 1 99 10 99 32 77 21 CH2FCF2CF2CF2CF2CH2F 99.4 1 99 10 99 32 77 21 CHFCF2CF2CF2CF2CH3 86.1 1 99 10 99 32 77 21 CH3CF2CF2CF3 16.8 1 80 10 80 28 63 10 CH2FCHFCF2CF3 38 1 95 10 95 31 74 16 CH2HCF2CHFCF3 42.6 1 99 10 99 32 77 17 CH2FCF2CH2CF3 44.7 1 99 10 99 32 77 17 CF2HCH2CF2CF3 40.2 1 99 10 99 32 77 17 CF2HCHFCHFCF3 51.9 1 99 10 99 32 77 18 CF3CH2CHFCF3 41.5 1 99 10 99 32 77 17 CH2FCF2CF2CF2H 44.7 1 99 10 99 32 77 17 CF2HCHFCF2CF2H 54.7 1 99 10 99 32 77 18 CF3CF2CHFCH2CF3 65.3 1 99 10 99 32 77 21 CF3CH2CF2CHFCF3 68.6 1 99 10 99 32 77 21 CH3CHFCH2CF2CF3 66.5 1 99 10 99 32 77 21 CF3CHFCHFCHFCF3 77 1 99 10 99 32 77 21 CF3CH2CF2CF2CHF2 71.6 1 99 10 99 32 77 21 CF3CHFCHFCF2CHF2 80.6 1 99 10 99 32 77 21 CF3CF2CH2CF2CHF2 70.5 1 99 10 99 32 77 21 CF3CHFCF2CUFCHF2 79.5 1 99 10 99 32 77 21 CF3CF2CHFCHFCHF2 76.5 1 99 10 99 32 77 21 CF3CF2CF2CH2CHF2 63.6 1 99 10 99 32 77 21 CF3CF2CF2CHFCH2F 62.3 1 99 10 99 32 77 21 CF3CF2CHFCF2CH2F 68.1 1 99 10 99 32 77 21 CF3CHFCF2CF2CH2F 70.3 1 99 10 99 32 77 21 CF3CF2CF2CF2CH3 41.9 1 99 10 99 32 77 21 CHF2CF2CF2CHFCHF2 80.7 1 99 10 99 32 77 21 CHF2CF2CHFCF2CHF2 82.6 1 99 10 99 32 77 21 CHF2CF2CF2CF2CH2F 69.8 1 99 10 99 32 77 21 CH3(CF2)4CF3 67.1 1 99 10 99 32 77 21 CH2FCHF(CF2)3CF3 87.4 1 99 10 99 32 77 21 CH2FCF2CHFCF2CF2CF3 92.3 1 99 10 99 32 77 21 CH2FCF2CF2CHFCF2CF3 95.8 1 99 10 99 32 77 21 CH2F(CF2)3CHFCF3 95.4 1 99 10 99 32 77 21 CF2HCH2(CF2)3CF3 88.7 1 99 10 99 32 77 21 CF2HCHFCHFCF2CF2CF3 100.8 1 99 10 99 32 77 21 CF2HCHFCF2CHFCF2CF3 104.9 1 99 10 99 32 77 21 CF2HCHFCF2CF2CHFCF3 106.3 1 99 10 99 32 77 21 CF2HCF2CH2CF2CF2CF3 94 1 99 10 99 32 77 21 CF2HCF2CHFCHFCF2CF3 105.3 1 99 10 99 32 77 21 CF2HCF2CHFCF2CHFCF3 107.3 1 99 10 99 32 77 21 CF2HCF2CF2CH2CF2CF3 97.4 1 99 10 99 32 77 21 CF2HCF2CF2CHFCHFCF3 106.6 1 99 10 99 32 77 21 CF2H(CF2)3CH2CF3 96.7 1 99 10 99 32 77 21 CF3CH2CHFCF2CF2CF3 89.5 1 99 10 99 32 77 21 CF3CH2CF2CHFCF2CF3 94.1 1 99 10 99 32 77 21 CF3CHFCF2CF2CH2CF3 97.2 1 99 10 99 32 77 21 CF3CF2CF2CH2CHFCF3 89.9 1 99 10 99 32 77 21 CF3CHFCHFCHFCF2CF3 101.6 1 99 10 99 32 77 21 CF3CHFCF2CHFCHFCF3 105.4 1 99 10 99 32 77 21 CF3CHFCF2CH2CF2CF3 94.5 1 99 10 99 32 77 21 CF3CF2CH2CHFCF2CF3 90.2 1 99 10 99 32 77 21 CH2F(CF2)4CF2H 94.9 1 99 10 99 32 77 21 CF2HCHF(CF2)3CF2H 105.8 1 99 10 99 32 77 21 CF2HCF2CHFCF2CF2CF2H 108.5 1 99 10 99 32 77 21 CF3CHFCHFCF3 38.7 1 95 10 95 31 74 17 CF3CF2CF2CH2F 25.7 1 90 10 90 30 70 16 CF3CF2CHFCHF2 37.4 1 95 10 95 31 74 17 CF3CHFCF2CHF2 39.8 1 95 10 95 31 74 17 CF3CF2CH2CHF2 29.1 1 90 10 90 30 70 16 CHF2CF2CF2CHF2 40.1 1 95 10 95 31 74 17 CH2FCF2CF2CH2CF3 50.8 1 99 10 99 32 77 18 CF2HCHFCF2CF2CF3 61.7 1 99 10 99 32 77 19 CF2HCF2CHFCF2CF3 65.3 1 99 10 99 32 77 19 CF2HCF2CF2CHFCF3 65.8 1 99 10 99 32 77 19 CF3CH2CF2CF2CF3 52.6 1 99 10 99 32 77 19 CF3CF2CHFCHFCF3 63.3 1 99 10 99 32 77 20 CF3CHFCF2CHFCF3 64.6 1 99 10 99 32 77 20 CF3CF2CH2CF2CF3 55 1 99 10 99 32 77 19 CF2HCF2CF2CF2CF2H 65.3 1 99 10 99 32 77 20 CF3CF2CHFCHFCF2CF3 88 1 99 10 99 32 77 21 CF3CF2CF2CH2CF2CF3 78.4 1 99 10 99 32 77 21 CF3CHFCF2CF2CHFCF3 91.4 1 99 10 99 32 77 21 CF3CF2CHFCF2CHFCF3 90 1 99 10 99 32 77 21 CF3CHFCHFCF2CF2CF3 87.6 1 99 10 99 32 77 21 CF3CF2CF2CF2CH2CF3 77.7 1 99 10 99 32 77 21 CF3CF2CF2CF2CHFCHF2 86.8 1 99 10 99 32 77 21 CF3CF2CF2CHFCF2CHF2 89.5 1 99 10 99 32 77 21 CF3CF2CHFCF2CF2CHF2 91.2 1 99 10 99 32 77 21 CF3CHFCF2CF2CF2CHF2 90.9 1 99 10 99 32 77 21 CF3CF2CF2CF2CF2CH2F 75.9 1 99 10 99 32 77 21 CF2HCF2CF2CF2CF2CHF2 90.4 1 99 10 99 32 77 21 CF2HCF2CF2CF2CF2CF3 71.4 1 99 10 99 32 77 21 CF3CHFCF2CF2CF2CF3 71.9 1 99 10 99 32 77 21 CF3CF2CHFCF2CF2CF3 72.2 1 99 10 99 32 77 21 CF2HCF2CF2CF3 21.1 1 90 10 80 28 63 15 CF3CHFCF2CF3 22.5 1 90 10 80 28 63 15 CF2HCF2CF3 −3.14 1 60 10 50 20 40 −6 CF3CHFCF3 −2.99 1 60 10 50 20 40 −6

TABLE 4 245fa azeotropes at 25° C. 245fa Preferred 245fa More Preferred 245fa Most preferred Azeo NBP = 15.3° C. VP = 1.43 atm Compositions wt % Compositions wt % Compositions wt. % NBP (° C.) STRUCTURE est. BP (° C.) Lower Upper Lower Upper Lower Upper (±1) CF3CF2CF2CH2CH3 46.3 60 99 70 99 77 92 12 CF3CF2CH2CF2CH3 59.4 65 99 75 99 81 93 13 CF3CF2CHFCHFCH3 61.7 66 99 76 99 82 93 13 CF2CH2CF2CF2CH3 67.2 68 99 78 99 84 94 13 CF3CHFCF2CHFCH3 68 69 99 79 99 84 94 13 CF3CHFCHFCF2CH3 72.9 70 99 80 99 85 94 14 CF3CF2CHFCH2CH2F 70 69 99 79 99 84 94 14 CF3CF2CH2CHFCH2F 75.2 71 99 81 99 86 95 14 CF3CHFCF2CH2CH2F 76.8 72 99 82 99 86 95 14 CF3CHFCH2CF2CH2F 83.1 74 99 84 99 87 95 14 CF3CH2CF2CHFCH2F 84.2 74 99 84 99 88 95 14 CF3CH2CHFCF2CH2F 85.4 74 99 84 99 88 95 14 CF3CHFCHFCHFCH2F 89.1 75 99 85 99 89 96 14 CF3CF2CH2CH2CHF2 72.5 70 99 80 99 85 94 14 CF3CH2CH2CF2CHF2 80.4 73 99 83 99 87 95 14 CF3CH2CF2CH2CHF2 82 73 99 83 99 87 95 14 CF3CHFCHFCH2CHF2 86.5 75 99 85 99 88 95 14 CF3CHFCH2CHFCHF2 87.7 75 99 85 99 88 95 14 CF3CH2CHFCHFCHF2 90.4 76 99 86 99 89 96 14 CF3CH2CH2CHFCF3 72.9 70 99 80 99 85 94 14 CF3CH2CHFCH2CF3 75.7 71 99 81 99 86 95 14 CH2FCF2CF2CF2CH3 65.4 68 99 78 99 83 94 14 CH2FCH2CF2CF2CHF2 79.7 73 99 83 99 87 95 14 CH2FCF2CF2CH2CHF2 87.1 75 99 85 99 88 95 14 CH2FCF2CH2CF2CHF2 87.2 75 99 85 99 88 95 14 CH2FCHFCHFCF2CHF2 92.8 76 99 86 99 89 96 14 CH2FCHFCF2CHFCHF2 95 77 99 87 99 90 96 14 CH2FCF2CHFCHFCHF2 96.6 77 99 87 99 90 96 14 CHF2CF2CF2CHFCH3 69.2 69 99 79 99 84 94 14 CHF2CF2CHFCF2CH3 74.8 71 99 81 99 85 94 14 CHF2CHFCF2CF2CH3 76.3 71 99 81 99 86 95 14 CHF2CF2CHFCH2CHF2 91.9 76 99 86 99 89 96 14 CHF2CHFCF2CH2CHF2 94.6 77 99 87 99 90 96 14 CHF2CF2CH2CHFCHF2 93.6 76 99 86 99 90 96 14 CHF2CHFCHFCHFCHF2 103.4 79 99 89 99 91 96 14 CH2FCHFCF2CF2CH2F 85.8 74 99 84 99 88 95 14 CH2FCF2CHFCF2CH2F 88.1 75 99 85 99 88 95 14 CF3CH2CH2CF3 40.7 61 99 71 99 78 92 12 CF3CHFCH2CHF2 50.8 66 99 76 99 82 93 12 CF3CH2CHFCHF2 53 67 99 77 99 82 93 12 CF3CF2CH2CH2F 37.3 60 99 70 99 77 92 11 CF3CHFCHFCH2F 50.8 66 99 76 99 82 93 12 CF3CH2CF2CH2F 45.8 64 99 74 99 80 93 12 CHF2CH2CF2CHF2 55.7 68 99 78 99 83 94 12 CHF2CHFCHFCHF2 65.1 71 99 81 99 86 95 13 CHF2CF2CHFCH2F 55.3 68 99 78 99 83 94 13 CHF2CHFCF2CH2F 57.5 69 99 79 99 84 94 13 CH2FCF2CF2CH2F 49.2 65 99 75 99 81 93 12 CHF2CF2CF2CH3 35.8 59 99 69 99 77 92 11 CF3CF2CHFCH3 26 54 99 64 99 73 90 11 CF3CHFCF2CH3 32 57 99 67 99 75 91 11 CF3CHFCHFCF2CHFCH2F 120.9 79 99 89 99 91 96 14 CF3CH2CF2CF2CHFCH2F 112.7 77 99 87 99 90 96 14 CF3CF2CHFCH2CF2CH2F 106.9 76 99 86 99 89 96 14 CF3CHFCF2CH2CF2CH2F 111.2 77 99 87 99 90 96 14 CF3CF2CH2CHFCF2CH2F 110.3 77 99 87 99 90 96 14 CF3CHFCHFCHFCF2CH2F 121.8 79 99 89 99 92 97 14 CF3CH2CF2CFHCF2CH2F 114.2 77 99 87 99 90 96 14 CF3CHFCH2CF2CF2CH2F 113.4 77 99 87 99 90 96 14 CF3CH2CHFCF2CF2CH2F 113.1 77 99 87 99 90 96 14 CF3CHFCH2CF2CHFCHF2 120.9 79 99 89 99 91 96 14 CF3CH2CHFCF2CHFCHF2 122.2 79 99 89 99 92 97 14 CF2CF2CH2CH2CF2CHF2 104.6 75 99 85 99 89 96 14 CF3CHFCHFCH2CF2CHF2 117.8 78 99 88 99 91 96 14 CF3CH2CF2CH2CF2CHF2 112.4 77 99 87 99 90 96 14 CF3CHFCH2CHFCF2CHF2 117.3 78 99 88 99 91 96 14 CF3CH2CH2CF2CF2CHF2 107.3 76 99 86 99 89 96 14 CF3CH2CHFCHFCF2CHF2 119.2 79 99 89 99 91 96 14 CF3CF2CF2CF2CH2CH3 71.4 65 99 75 99 81 93 14 CF3CF2CF2CHFCHFCH3 86 70 99 80 99 85 94 14 CF3CF2CHFCF2CHFCH3 93.5 72 99 82 99 86 95 14 CF3CHFCF2CF2CHFCH3 94.9 73 99 83 99 87 95 14 CF3CF2CF2CH2CF2CH3 82.8 69 99 79 99 84 94 14 CF3CF2CHFCHFCF2CH3 97.5 73 99 83 99 87 95 14 CF3CHFCF2CHFCF2CH3 99.6 74 99 84 99 88 95 14 CF3CF2CH2CF2CF2CH3 93 72 99 82 99 86 95 14 CF3CHFCHFCF2CF2CH3 102.3 75 99 85 99 88 95 14 CF3CH2CF2CF2CF2CH3 92.4 72 99 82 99 86 95 14 CHF2CF2CF2CHFCH2CHF2 117.8 78 99 88 99 91 96 14 CHF2CF2CHFCF2CH2CHF2 122.4 79 99 89 99 92 97 14 CHF2CHFCF2CF2CH2CHF2 123.1 79 99 89 99 92 97 14 CF3CF2CHFCH2CHFCHF2 120.4 79 99 89 99 91 96 14 CHF2CF2CHFCHFCHFCHF2 132.1 81 99 91 99 93 97 14 CHF2CHFCF2CHFCHFCFIF2 133.5 81 99 91 99 93 97 14 CGF2CF2CH2CF2CHFCHF2 124.9 80 99 90 99 92 97 14 CHF2CF2CHFCH2CF2CHF2 123.1 79 99 89 99 92 97 14 CHF2CF2CF2CF2CH2CH2F 104.8 75 99 85 99 89 96 14 CHF2CF2CF2CHFCHFCH2F 118.7 78 99 88 99 91 96 14 CHF2CF2CHFCF2CHFCH2F 122.9 79 99 89 99 92 97 14 CHF2CHFCF2CF2CHFCH2F 121.8 79 99 89 99 92 97 14 CHF2CF2CF2CH2CF2CH2F 114.1 77 99 87 99 90 96 14 CHF2CF2CHFCHFCF2CH2F 125.4 80 99 90 99 92 97 14 CHF2CHFCF2CHFCF2CH2F 125 80 99 90 99 92 97 14 CHF2CF2CH2CF2CF2CH2F 117.5 78 99 88 99 91 96 14 CHF2CHFCHFCF2CF2CH2F 124.2 80 99 90 99 92 97 14 CHF2CH2CF2CF2CF2CH2F 112.2 77 99 87 99 90 96 14 CF2HCF2CF2CF2CHFCH3 94.4 72 99 82 99 87 95 14 CF2HCF2CF2CHFCF2CH3 100.8 74 99 84 99 88 95 14 CHF2CF2CHFCF2CF2CH3 104.2 75 99 85 99 89 96 14 CHF2CHFCF2CF2CF2CH3 101.4 74 99 84 99 88 95 14 CH2FCF2CF2CF2CF2CH3 90.6 71 99 81 99 86 95 14 CH2FCF2CF2CF2CHFCH2F 110.9 77 99 87 99 90 96 14 CH2FCF2CF2CHFCF2CH2F 115.9 78 99 88 99 91 96 14 CF3CH2CH2CHFCF2CF3 96.7 73 99 83 99 87 95 14 CF3CH2CH2CF2CHFCF3 104.4 75 99 85 99 89 96 14 CF3CF2CH2CHFCH2CF3 100.7 74 99 84 99 88 95 14 CF3CHFCHFCHFCH2CF3 115.5 78 99 88 99 91 96 14 CF3CH2CF2CHFCH2CF3 111.4 77 99 87 99 90 96 14 CF3CHFCH2CF2CH2CF3 108.4 76 99 86 99 89 96 14 CF3CHFCH2CH2CF2CF3 97.1 73 99 83 99 87 95 14 CF3CHFCHFCH2CHFCF3 112 77 99 87 99 90 96 14 CF3CF2CF2CH2CH2CHF2 95.9 73 99 83 99 87 95 14 CF3CF2CHFCHFCH2CHF2 111.2 77 99 87 99 90 96 14 CF3CHFCF2CHFCH2CHF2 116.6 78 99 88 99 91 96 14 CF3CF2CH2CF2CH2CHF2 107.9 76 99 86 99 89 96 14 CF3CHFCHFCF2CH2CHF2 120.5 79 99 89 99 91 96 14 CF3CH2CF2CF2CH2CHF2 114 77 99 87 99 90 96 14 CF3CF2CHFCH2CHFCHF2 111.5 77 99 87 99 90 96 14 CF3CHFCF2CH2CHFCHF2 117.4 78 99 88 99 91 96 14 CF3CF2CH2CHFCHFCHF2 115.4 78 99 88 99 91 96 14 CF3CHFCHFCHFCHFCHF2 128.5 80 99 90 99 93 97 14 CF3CH2CF2CHFCHFCHF2 122.7 79 99 89 99 92 97 14 CF3CF2CF2CHFCH2CH2F 94.3 72 99 82 99 87 95 14 CF3CF2CHFCF2CH2CH2F 102.3 75 99 85 99 88 95 14 CF3CHFCF2CF2CH2CH2F 105.3 75 99 85 99 89 96 14 CF3CF2CF2CH2CHFCH2F 98.6 74 99 84 99 87 95 14 CF3CF2CHFCHFCHFCH2F 113.8 77 99 87 99 90 96 14 CF3CHFCF2CHFCHFCH2F 117.5 78 99 88 99 91 96 14 CF3CF2CH2CF2CHFCH2F 110 76 99 86 99 90 96 14 CH3CHFCF2CF2CF3 50.2 60 99 70 99 77 92 12 CH3CF2CFHCF2CF3 57.5 63 99 73 99 79 92 12 CH3CF2CF2CHFCF3 60.9 64 99 74 99 80 93 13 CH2FCH2CF2CF2CF3 60.7 64 99 74 99 80 93 13 CH2FCHFCHFCF2CF3 75.5 69 99 79 99 84 94 14 CH2FCHFCF2CHFCF3 80.1 71 99 81 99 85 94 14 CH2FCF2CH2CF2CF3 71.6 68 99 78 99 83 94 14 CH2FCF2CHFCHFCF3 83.5 72 99 82 99 86 95 14 CH2FCF2CF2CH2CF3 76.1 70 99 80 99 84 94 14 CF2HCH2CHFCF2CF3 74.6 69 99 79 99 84 94 14 CF2HCH2CF2CHFCF3 79.7 71 99 81 99 85 94 14 CF2HCHFCH2CF2CF3 77.9 70 99 80 99 85 94 14 CF2HCHFCHFCHFCF3 90.2 74 99 84 99 88 95 14 CF2HCHFCF2CH2CF3 83.5 72 99 82 99 86 95 14 CF2HCF2CH2CFHCF3 82 71 99 81 99 86 95 14 CF2HCF2CHFCH2CF3 82.6 72 99 82 99 86 95 14 CF3CH2CH2CF2CF3 64.8 66 99 76 99 81 93 14 CF3CH2CHFCHFCF3 77.2 70 99 80 99 85 94 14 CF3CH2CF2CH2CF3 71 68 99 78 99 83 94 14 CF3CHFCH2CHFCF3 76.2 70 99 80 99 84 94 14 CH2FCF2CHFCF2CF2H 85.4 73 99 83 99 87 95 14 CH2FCF2CF2CHFCF2H 85.2 72 99 82 99 87 95 14 CH2FCHFCF2CF2CF2H 81.3 71 99 81 99 86 95 14 CH3CF2CF2CF2CF2H 60.9 64 99 74 99 80 93 14 CF2HCH2CF2CF2CF2H 82.6 72 99 82 99 86 95 14 CF2HCHFCHFCF2CF2H 93.8 75 99 85 99 88 95 14 CF2HCHFCF2CHFCF2H 94.3 75 99 85 99 89 96 14 CF2HCF2CH2CF2CF2H 86.1 73 99 83 99 87 95 14 CH2FCF2CF2CF2CH2F 74.3 69 99 79 99 84 94 14 CF3CF2CF2CH2CH2CF3 88.3 69 99 79 99 84 94 14 CF3CF2CHFCHFCH2CF3 101.9 73 99 83 99 87 95 14 CF3CHFCF2CHFCH2CF3 107.3 75 99 85 99 88 95 14 CF3CF2CH2CF2CH2CF3 96.9 72 99 82 99 86 95 14 CF3CHFCHFCF2CH2CF3 109.5 75 99 85 99 89 96 14 CF3CH2CF2CF2CH2CF3 103 73 99 83 99 87 95 14 CF3CHFCH2CHFCF2CF3 100 73 99 83 99 87 95 14 CF3CHFCH2CF2CHFCF3 10.6 34 99 44 99 58 85 14 CF3CHFCHFCH2CF2CF3 102.2 73 99 83 99 87 95 14 CF3CHFCHFCHFCHFCF3 115.3 76 99 86 99 90 96 14 CF3CF2CH2CH2CF2CF3 89 69 99 79 99 84 94 14 CF3CF2CF2CHFCH2CHF2 98.8 72 99 82 99 86 95 14 CF3CF2CHFCF2CH2CHF2 105.1 74 99 84 99 88 95 14 CF3CHFCF2CF2CHFCHF2 108.2 75 99 85 99 88 95 14 CF3CF2CF2CH2CHFCHF2 101.4 73 99 83 99 87 95 14 CF3CF2CHFCHFCHFCHF2 114.8 76 99 86 99 89 96 14 CF3CHFCF2CHFCHFCHF2 118.6 77 99 87 99 90 96 14 CF3CF2CH2CF2CHFCHF2 109.4 75 99 85 99 89 96 14 CF3CHFCHFCF2CHFCHF2 120.3 78 99 88 99 90 96 14 CF3CH2CF2CF2CHFCHF2 112.1 76 99 86 99 89 96 14 CF3CF2CHFCH2CF2CHF2 105.8 74 99 84 99 88 95 14 CF3CHFCF2CH2CF2CHF2 110.1 75 99 85 99 89 96 14 CF3CF2CH2CHFCF2CHF2 107.5 75 99 85 99 88 95 14 CF3CHFCHFCHFCF2CHF2 118.9 77 99 87 99 90 96 14 CF3CH2CF2CHFCF2CHF2 111.4 76 99 86 99 89 96 14 CF3CHFCH2CF2CF2CHF2 108.9 75 99 85 99 88 95 14 CF3CH2CHFCF2CF2CHF2 108.5 75 99 85 99 88 95 14 CF3CF2CF2CF2CH2CH2F 85.8 68 99 78 99 83 94 14 CF3CF2CF2CHFCHFCH2F 99.7 73 99 83 99 87 95 14 CF3CF2CHFCF2CHFCH2F 105.6 74 99 84 99 88 95 14 CF3CHFCF2CF2CHFCH2F 106.9 74 99 84 99 88 95 14 CF3CH2CF2CH2CF2CH2F 95.1 71 99 81 99 86 95 14 CF3CF2CHFCHFCF2CH2F 108.1 75 99 85 99 88 95 14 CF3CHFCF2CHFCF2CH2F 110.1 75 99 85 99 89 96 14 CF3CF2CH2CF2CF2CH2F 101.9 73 99 83 99 87 95 14 CF3CHFCHFCF2CF2CH2F 111.4 76 99 86 99 89 96 14 CHF2CF2CHFCF2CF2CH2F 101.2 73 99 83 99 87 95 14 CF3CF2CF2CF2CHFCH3 75.4 65 99 75 99 81 93 14 CF3CF2CF2CHFCF2CH3 81.8 67 99 77 99 83 94 14 CF3CF2CHFCF2CF2CH3 86.9 69 99 79 99 84 94 14 CF3CHFCF2CF2CF2CH3 86.6 69 99 79 99 84 94 14 CHF2CF2CF2CHFCHFCHF2 119.8 77 99 87 99 90 96 14 CHF2CF2CHFCF2CHFCHF2 122.2 78 99 88 99 91 96 14 CHF2CHFCF2CF2CHFCHF2 121.2 78 99 88 99 91 96 14 CHF2CF2CF2CH2CF2CHF2 113 76 99 86 99 89 96 14 CHF2CF2CHFCHFCF2CHF2 122.6 78 99 88 99 91 96 14 CHF2CH2CF2CF2CF2CHF2 107.7 75 99 85 99 88 95 14 CHF2CF2CF2CF2CHFCH2F 106.4 74 99 84 99 88 95 14 CHF2CF2CF2CHFCF2CH2F 111.4 76 99 86 99 89 96 14 CHF2CF2CHFCF2CF2CH2F 113.1 76 99 86 99 89 96 14 CHF2CHFCF2CF2CF2CH2F 110.3 75 99 85 99 89 96 14 CH2FCF2CF2CF2CF2CH2F 99.4 72 99 82 99 87 95 14 CHFCF2CF2CF2CF2CH3 86.1 68 99 78 99 84 94 14 CH3CF2CF2CF3 16.8 46 99 56 99 67 88 9 CH2FCHFCF2CF3 38 58 99 68 99 76 91 11 CH2FCF2CHFCF3 42.6 60 99 70 99 77 92 11 CH2FCF2CH2CF3 44.7 61 99 71 99 78 92 11 CF2HCH2CF2CF3 40.2 59 99 69 99 76 91 11 CF2HCHFCHFCF3 51.9 64 99 74 99 80 93 11 CF3CH2CHFCF3 41.5 59 99 69 99 77 92 11 CH2FCF2CF2CF2H 44.7 61 99 71 99 78 92 11 CF2HCHFCF2CF2H 54.7 65 99 75 99 81 93 12 CF3CF2CHFCH2CF3 65.3 64 99 74 99 80 93 13 CF3CH2CF2CHFCF3 68.6 65 99 75 99 81 93 13 CF3CHFCH2CF2CF3 66.5 64 99 74 99 81 93 13 CF3CHFCHFCHFCF3 77 68 99 78 99 83 94 13 CF3CH2CF2CF2CHF2 71.6 66 99 76 99 82 93 13 CF3CHFCHFCF2CHF2 80.6 69 99 79 99 84 94 13 CF3CF2CH2CF2CHF2 70.5 66 99 76 99 82 93 13 CF3CHFCF2CHFCHF2 79.5 69 99 79 99 84 94 13 CF3CF2CHFCHFCHF2 76.5 68 99 78 99 83 94 13 CF3CF2CF2CH2CHF2 63.6 63 99 73 99 80 93 13 CF3CF2CF2CHFCH2F 62.3 63 99 73 99 79 92 13 CF3CF2CHFCF2CH2F 68.1 65 99 75 99 81 93 13 CF3CHFCF2CF2CH2F 70.3 66 99 76 99 82 93 13 CF3CF2CF2CF2CH3 41.9 54 99 64 99 73 90 13 CHF2CF2CF2CHFCHF2 80.7 69 99 79 99 84 94 13 CHF2CF2CHFCF2CHF2 82.6 70 99 80 99 85 94 13 CHF2CF2CF2CF2CH2F 69.8 66 99 76 99 81 93 13 CH3(CF2)4CF3 67.1 60 99 70 99 77 92 14 CH2FCHF(CF2)3CF3 87.4 67 99 77 99 83 94 14 CH2FCF2CHFCF2CF2CF3 92.3 69 99 79 99 84 94 14 CH2FCF2CF2CHFCF2CF3 95.8 70 99 80 99 85 94 14 CH2F(CF2)3CHFCF3 95.4 70 99 80 99 85 94 14 CF2HCH2(CF2)3CF3 88.7 68 99 78 99 83 94 14 CF2HCHFCHFCF2CF2CF3 100.8 71 99 81 99 86 95 14 CF2HCHFCF2CHFCF2CF3 104.9 73 99 83 99 87 95 14 CF2HCHFCF2CF2CHFCF3 106.3 73 99 83 99 87 95 14 CF2HCF2CH2CF2CF2CF3 94 69 99 79 99 84 94 14 CF2HCF2CHFCHFCF2CF3 105.3 73 99 83 99 87 95 14 CF2HCF2CHFCF2CHFCF3 107.3 73 99 83 99 87 95 14 CF2HCF2CF2CH2CF2CF3 97.4 71 99 81 99 85 94 14 CF2HCF2CF2CHFCHFCF3 106.6 73 99 83 99 87 95 14 CF2H(CF2)3CH2CF3 96.7 70 99 80 99 85 94 14 CF3CH2CHFCF2CF2CF3 89.5 68 99 78 99 83 94 14 CF3CH2CF2CHFCF2CF3 94.1 70 99 80 99 84 94 14 CF3CHFCF2CF2CH2CF3 97.2 70 99 80 99 85 94 14 CF3CF2CF2CH2CHFCF3 89.9 68 99 78 99 83 94 14 CF3CHFCHFCHFCF2CF3 101.6 72 99 82 99 86 95 14 CF3CHFCF2CHFCHFCF3 105.4 73 99 83 99 87 95 14 CF3CHFCF2CH2CF2CF3 94.5 70 99 80 99 84 94 14 CF3CF2CH2CHFCF2CF3 90.2 68 99 78 99 83 94 14 CH2F(CF2)4CF2H 94.9 70 99 80 99 85 94 14 CF2HCHF(CF2)3CF2H 105.8 73 99 83 99 87 95 14 CF2HCF2CHFCF2CF2CF2H 108.5 74 99 84 99 87 95 14 CF3CHFCHFCF3 38.7 56 99 66 99 74 91 11 CF3CF2CF2CH2F 25.7 49 99 59 99 69 89 10 CF3CF2CHFCHF2 37.4 55 99 65 99 74 91 11 CF3CHFCF2CHF2 39.8 56 99 66 99 74 91 11 CF3CF2CH2CHF2 29.1 51 99 61 99 70 89 11 CHF2CF2CF2CHF2 40.1 56 99 66 99 75 91 11 CH2FCF2CF2CH2CF3 50.8 56 99 66 99 74 91 13 CF2HCHFCF2CF2CF3 61.7 61 99 71 99 78 92 14 CF2HCF2CHFCF2CF3 65.3 62 99 72 99 79 92 14 CF2HCF2CF2CHFCF3 65.8 62 99 72 99 79 92 14 CF3CH2CF2CF2CF3 52.6 57 99 67 99 75 91 14 CF3CF2CHFCHFCF3 63.3 61 99 71 99 78 92 14 CF3CHFCF2CHFCF3 64.6 62 99 72 99 79 92 14 CF3CF2CH2CF2CF3 55 58 99 68 99 76 91 14 CF2HCF2CF2CF2CF2H 65.3 62 99 72 99 79 92 14 CF3CF2CHFCHFCF2CF3 88 66 99 76 99 82 93 14 CF3CF2CF2CH2CF2CF3 78.4 63 99 73 99 79 92 14 CF3CHFCF2CF2CHFCF3 91.4 67 99 77 99 83 94 14 CF3CF2CHFCF2CHFCF3 90 67 99 77 99 82 93 14 CF3CHFCHFCF2CF2CF3 87.6 66 99 76 99 82 93 14 CF3CF2CF2CF2CH2CF3 77.7 63 99 73 99 79 92 14 CF3CF2CF2CF2CHFCHF2 86.8 66 99 76 99 82 93 14 CF3CF2CF2CHFCF2CHF2 89.5 67 99 77 99 82 93 14 CF3CF2CHFCF2CF2CHF2 91.2 67 99 77 99 83 94 14 CF3CHFCF2CF2CF2CHF2 90.9 67 99 77 99 83 94 14 CF3CF2CF2CF2CF2CH2F 75.9 62 99 72 99 79 92 14 CF2HCF2CF2CF2CF2CHF2 90.4 67 99 77 99 83 94 14 CF2HCF2CF2CF2CF2CF3 71.4 59 99 69 99 76 91 14 CF2CHFCF2CF2CF2CF3 71.9 59 99 69 99 77 92 14 CF3CF2CHFCF2CF2CF3 72.2 59 99 69 99 77 92 14 CF2HCF2CF2CF3 21.1 44 99 54 95 65 85 10 CF3CHFCF2CF3 22.5 45 99 55 95 65 85 10 CF2HCF2CF3 −3.14 36 90 46 85 56 75 −7 CF3CHFCF3 −2.99 37 90 47 85 56 75 −7

EXAMPLE 1

This example shows that constant boiling HFC-245 and hydrofluorocarbon blends have certain advantages when compared to other refrigerants currently used in certain refrigeration cycles. The theoretical performance of a refrigerant at specific operating conditions nay be estimated from the thermodynamic performance of a refrigerant using standard refrigeration cycle analysis techniques. See R. C. Downing, Fluorocarbon Refrigerants Handbook, Chapter 3, Prentice-Hall, 1988. The coefficient of performance, COP, is a universally accepted measure especially useful in representing the relative thermodynamic efficiency of a refrigerant in a specific heating or cooling cycle involving evaporation or condensation of the refrigerant. In refrigeration engineering, this term expresses the ratio of useful refrigeration to the energy applied by the compressor in compressing vapor. The capacity of a refrigerant represents the volume efficiency of the refrigerant. To a compressor engineer, this value expresses the capability of a compressor to pump quantities of heat for a given volumetric flow rate of refrigerant. In other words, given a specific compressor, a refrigerant with a higher capacity will deliver more cooling or heating power.

This type of calculation is performed for Blend 1, HFC-245ca and CF₃CH₂CHFCF₃, and Blend 2, HFC-245fa and CF₂HCHFCHFCF₃. Table 5 lists the COP and capacity of the various blends at typical chiller conditions in a saturated cycle and at 40° F. evaporator temperature and 100° F. condensing temperature and a compressor efficiency of 80% and a displacement of 1000 cubic feet per hour.

TABLE 5 COP Capacity (BTU/hr) Blend 1 5.57 11,577 Blend 2 5.90 11,463

As can be seen, the HFC-245 compositions of this invention are useful refrigerants.

In addition to being minimally segregating, the compositions of this invention overcome the potential drawbacks of the single component refrigerants in that the present blends likely will not exhibit flame limits when tested in air at ambient conditions using the ASTM E-681 method as specified in the american Society of Heating, Refrigerating and Air Conditioning Engineers (ASHRAE) Standard 34-1992.

While only a few embodiments of the invention have been shown and described herein, it will become apparent to those skilled in the art that various modifications and changes can be made in the present invention to azeotropic-like mixtures of fluorinated organic compounds and their use in heating and cooling and as blowing agents in polymers. All such modification and changes coming within the scope of the appended claims are intended to be carried out thereby. 

We claim:
 1. A process to produce a polyurethane foam or a polyisocyanurate foam, which processes comprises: (A) combining a mixture of compounds needed to produce a polyurethane with a sufficient quantity of the azeotrope-like mixture as a blowing agent, under reaction conditions which produce a foamed polyurethane; or (B) combining a mixture of compounds needed to produce a polyisocyanurate with a sufficient quantity of the azeotrope-like mixture as a blowing agent, under reaction conditions which produce a foamed polyisocyanurate; wherein said blowing agent is an azeotrope-like mixture, which mixture comprises: (a) pentafluoropropane; and (b) a hydrofluorocarbon of the formula: C_(x)F_(y)H_(z) wherein x is 3, 4, 5, or 6 and y and z are each independently 1 or a positive whole number such that the result of y/(y+z) is greater than 0.67.
 2. The process of claim 1 wherein the hydrofluorocarbon is selected from 1,1,2,2,3-pentafluoropropane; 1,1,2,3,3-pentafluoropropane; 1,1,1,2,3-pentafluoropropane; 1,1,1,3,3-pentafluoropropane; or mixtures thereof.
 3. The process of claim 2 wherein the hydrofluorocarbon is selected from 1,1,2,2,3-pentafluoropropane or 1,1,1,3,3-pentafluoropropane.
 4. The process of claim 2 wherein the pentafluoropropane is 1,1,1,3,3-pentafluoropropane.
 5. The process of claim 1 wherein the hydrofluorocarbon is 1,1,2,2,3-pentafluoropropane.
 6. The process of claim 1 wherein the hydrofluorocarbon is 1,1,2,3,3-pentafluoropropane. 